A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides
about
Palladium-Catalyzed Direct Synthesis of Organoboronic AcidsRational exploration of N-heterocyclic carbene (NHC) palladacycle diversity: a highly active and versatile precatalyst for Suzuki-Miyaura coupling reactions of deactivated aryl and alkyl substrates.Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.Mild Pd-catalyzed aminocarbonylation of (hetero)aryl bromides with a palladacycle precatalystWater-mediated catalyst preactivation: an efficient protocol for C-N cross-coupling reactions.Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.Replacing conventional carbon nucleophiles with electrophiles: nickel-catalyzed reductive alkylation of aryl bromides and chloridesStereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides.Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions.A multiligand based Pd catalyst for C-N cross-coupling reactions.Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions.Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric SynthesisPalladium-catalyzed C,N-cross coupling reactions of 3-halo-2-aminopyridines.Palladium-catalyzed amination of unprotected halo-7-azaindolesSimple, Efficient Protocols for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine.Efficient Pd-catalyzed amination reactions for heterocycle functionalizationMechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates.Completely N1-selective palladium-catalyzed arylation of unsymmetric imidazoles: application to the synthesis of nilotinibTotal Synthesis of (-)-Nodulisporic Acid D.Palladium-Catalyzed Coupling of Functionalized Primary and Secondary Amines with Aryl and Heteroaryl Halides: Two Ligands Suffice in Most CasesTetramethyleneethane Equivalents: Recursive Reagents for Serialized Cycloadditions.STILLE CROSS-COUPLING REACTIONS OF ARYL MESYLATES AND TOSYLATES USING A BIARYLPHOSPHINE BASED CATALYST SYSTEM.Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides.An efficient process for pd-catalyzed C-N cross-coupling reactions of aryl iodides: insight into controlling factors.A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides.An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand.Suzuki-Miyaura cross-coupling optimization enabled by automated feedback.A Divalent Protecting Group for Benzoxaboroles.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.Cross-coupling in flow.The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions.Metal-organic frameworks catalyzed C-C and C-heteroatom coupling reactions.Stereospecific functionalizations and transformations of secondary and tertiary boronic esters.Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy.NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides.
P2860
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P2860
A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
A new class of easily activate ...... ive addition of aryl chlorides
@en
type
label
A new class of easily activate ...... ive addition of aryl chlorides
@en
prefLabel
A new class of easily activate ...... ive addition of aryl chlorides
@en
P2093
P2860
P356
P1476
A new class of easily activate ...... ive addition of aryl chlorides
@en
P2093
Brett P Fors
Mark R Biscoe
Stephen L Buchwald
P2860
P304
P356
10.1021/JA801137K
P407
P577
2008-05-01T00:00:00Z