Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
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Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetalsErosion of stereochemical control with increasing nucleophilicity: O-glycosylation at the diffusion limit.Macrocyclic bis-thioureas catalyze stereospecific glycosylation reactions.Solvent effects in the nucleophilic substitutions of tetrahydropyran acetals promoted by trimethylsilyl trifluoromethanesulfonate: trichloroethylene as solvent for stereoselective C- and O-glycosylations.Formal synthesis of (+)-sorangicin A.Participation of alkoxy groups in reactions of acetals: violation of the reactivity/selectivity principle in a Curtin-Hammett kinetic scenario.Nucleophilic addition to silyl-protected five-membered ring oxocarbenium ions governed by stereoelectronic effects.Mechanism of Glycosylation of Anomeric Sulfonium Ions.Synthesis and biological properties of the cytotoxic 14-membered macrolides aspergillide A and B.The influence of acceptor nucleophilicity on the glycosylation reaction mechanism.A quantitative approach to nucleophilic organocatalysis.Hydrogen-bonding catalysis and inhibition by simple solvents in the stereoselective kinetic epoxide-opening spirocyclization of glycal epoxides to form spiroketals.Do glycosyl sulfonium ions engage in neighbouring-group participation? A study of oxathiane glycosyl donors and the basis for their stereoselectivity.
P2860
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P2860
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 10 October 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
@en
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals.
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type
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Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
@en
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals.
@nl
prefLabel
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
@en
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals.
@nl
P2093
P2860
P356
P1433
P1476
Continuum of mechanisms for nucleophilic substitutions of cyclic acetals
@en
P2093
Jennifer R Krumper
K A Woerpel
Walter A Salamant
P2860
P304
P356
10.1021/OL8019956
P407
P577
2008-10-10T00:00:00Z