The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
about
Undirected, Homogeneous C-H Bond Functionalization: Challenges and OpportunitiesDecreasing Distortion Energies without Strain: Diazo-Selective 1,3-Dipolar CycloadditionsSubstituents on quinone methides strongly modulate formation and stability of their nucleophilic adducts.Cryptic post-transition state bifurcations that reduce the efficiency of lactone-forming Rh-carbenoid C-H insertions.Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetalsErosion of stereochemical control with increasing nucleophilicity: O-glycosylation at the diffusion limit.Participation of alkoxy groups in reactions of acetals: violation of the reactivity/selectivity principle in a Curtin-Hammett kinetic scenario.Biological reactive intermediates (BRIs) formed from botanical dietary supplementsSelectivity in supramolecular host-guest complexes.Continuum of mechanisms for nucleophilic substitutions of cyclic acetalsHeuristic thinking makes a chemist smart.Farewell to the HSAB treatment of ambident reactivity.Increasing the reactivity of nitrogen catalysts.Immunological Genome Project and systems immunology.Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTsElectronic tuning of site-selectivity.A quantitative approach to nucleophilic organocatalysis.Photochemical Stereocontrol Using Tandem Photoredox-Chiral Lewis Acid Catalysis.Organocatalytic stereoselective alpha-alkylation of aldehydes with stable carbocations.A novel approach for the evaluation of positive cooperative guest binding: kinetic consequences of structural tightening.Reactions of hexadehydro-Diels-Alder benzynes with structurally complex multifunctional natural products.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Kinetics screening of the N-alkylation of organic superbases using a continuous flow microfluidic device: basicity versus nucleophilicity.Sequential stereodivergent organocatalysis and programmed organocascades.First Principles Calculations for Hydrogenation of Acrolein on Pd and Pt: Chemoselectivity Depends on Steric Effects on the Surface.Structures and reactivities of O-methylated Breslow intermediates.
P2860
Q26746442-767B15FE-9AE8-4B04-B1A5-ABE222A934E6Q28817848-1512E8CB-C640-4A9C-B91C-8CF61848E76EQ33256397-1AEF130D-EDED-4289-9C55-86E6B8B8943BQ33562027-676EC620-6BF8-442A-BF50-50D5A373826DQ33683347-0B93ECC1-C870-4EDC-AC65-D35E1E858BF6Q33727064-40999E87-EE1E-4184-9E67-04BDC1A9721DQ36433009-D024750F-E5D6-4C64-B79B-C0E999273B4CQ36996161-63813042-622C-44D4-8BA7-7B209172A84EQ37057884-F2EA68AB-78DA-4AD8-A7B5-21FA4C9BF17AQ37147601-F6D4B17F-DA67-4DD3-95C6-9B3DA9B70F3EQ37737084-FFCA77AC-40FA-425B-AB25-DD1C89319CEFQ37897198-5420C424-4752-4A60-A563-650BE16E17A8Q37947516-5AB42790-A409-43B1-A852-1CEC0FA2F160Q38103082-EB2EC027-0B14-4D97-9452-BC652584F466Q41302083-EFD92456-D216-4107-856E-0749A43B57E4Q41856440-46B9EE4E-0358-4572-B1C5-5D7CD3ACEA48Q42084604-DDA3D9A2-EAA2-4DCD-A72C-0A223C1E3528Q42379295-3D061F60-83C5-4E1A-81E9-4CF4BE64A5E8Q42979627-77C9974C-49C7-4B3B-942A-748EC5000D17Q45106272-6F3CC5C7-FD85-4FAF-9FAF-7760CA9030AEQ46361623-DA36EB30-C7F8-4B4F-AE35-E091FDF9E9FBQ47245449-83C30939-B7B2-478F-AD51-1338109EF353Q51323566-3B4FD5D1-2CED-4482-AE1D-3101EA398748Q51755974-8A829911-9AB3-4071-BEB5-B2239F760053Q53640251-75B71F2B-C7DD-4301-B422-A89DCB8EE9D8Q53914356-B8188501-D681-4C48-9DE8-F4687F0134AA
P2860
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
description
2006 nî lūn-bûn
@nan
2006 թուականի Մարտին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի մարտին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@ast
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@en
type
label
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@ast
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@en
prefLabel
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@ast
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@en
P356
P1476
The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry
@en
P2093
Armin R. Ofial
Herbert Mayr
P304
P356
10.1002/ANIE.200503273
P407
P577
2006-03-13T00:00:00Z