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A fluorescence-based thermal shift assay identifies inhibitors of mitogen activated protein kinase kinase 4Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisSynthesis of (-)-epibatidine.Discovering New Reactions with N-Heterocyclic Carbene Catalysis.N-heterocyclic carbene-initiated alpha-acylvinyl anion reactivity: additions of alpha-hydroxypropargylsilanes to aldehydesAssembly of four diverse heterocyclic libraries enabled by Prins cyclization, Au-catalyzed enyne cycloisomerization, and automated amide synthesis.Intermolecular Cross-Acyloin Reactions by Fluoride-Promoted Additions of O-Silyl Thiazolium Carbinols.A Cooperative N-Heterocyclic Carbene/Palladium Catalysis System.Highly stereoselective Brønsted acid catalyzed synthesis of spirooxindole pyrans.N-Heterocyclic carbene-catalyzed enantioselective annulations: a dual activation strategy for a formal [4+2] addition for dihydrocoumarins.Discovery of 1,3,4-oxidiazole scaffold compounds as inhibitors of superoxide dismutase expression.Enantioselective β-Protonation by a Cooperative Catalysis Strategy.Pyranone natural products as inspirations for catalytic reaction discovery and developmentCooperative Lewis acid/N-heterocyclic carbene catalysisVirtual High-Throughput Screening To Identify Novel Activin Antagonists.A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations.MEK4 function, genistein treatment, and invasion of human prostate cancer cellsImpact of solvent polarity on N-heterocyclic carbene-catalyzed beta-protonations of homoenolate equivalentsMetal-organic framework materials as catalysts.Prins-type macrocyclizations as an efficient ring-closing strategy in natural product synthesis.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.Asymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.Studies on the synthesis of apoptolidin A. 1. Synthesis of the C(1)-C(11) fragment.Cooperative Catalysis and Activation with N-Heterocyclic Carbenes.Synthesis of (-)-okilactomycin by a Prins-type fragment-assembly strategy.Enantioselective synthesis of (-)-exiguolide by iterative stereoselective dioxinone-directed Prins cyclizations.N-heterocyclic carbene-catalyzed enantioselective Mannich reactions with alpha-aryloxyacetaldehydes.Concise syntheses of the abyssinones and discovery of new inhibitors of prostate cancer and MMP-2 expressionTotal synthesis and structure-activity investigation of the marine natural product neopeltolide.Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.Catalytic enantioselective total syntheses of bakkenolides I, J, and S: application of a carbene-catalyzed desymmetrization.Protonation of Homoenolate Equivalents Generated by N-Heterocyclic Carbenes.Catalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactonesFunctionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic applicationN-heterocyclic carbene-catalyzed oxidation of unactivated aldehydes to esters.Enantioselective annulations for dihydroquinolones by in situ generation of azolium enolatesHighly diastereo- and enantioselective additions of homoenolates to nitrones catalyzed by N-heterocyclic carbenes.Lewis acid-catalyzed conjugate additions of silyloxyallenes: a selective solution to the intermolecular Rauhut-Currier problem.N-heterocyclic-carbene-catalyzed synthesis of 2-aryl indoles.
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description
hulumtues
@sq
researcher
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wetenschapper
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հետազոտող
@hy
name
Karl A Scheidt
@ast
Karl A Scheidt
@en
Karl A Scheidt
@es
Karl A Scheidt
@nl
Karl A Scheidt
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type
label
Karl A Scheidt
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Karl A Scheidt
@en
Karl A Scheidt
@es
Karl A Scheidt
@nl
Karl A Scheidt
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prefLabel
Karl A Scheidt
@ast
Karl A Scheidt
@en
Karl A Scheidt
@es
Karl A Scheidt
@nl
Karl A Scheidt
@sl
P106
P21
P31
P496
0000-0003-4856-3569