Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesDesigning N-heterocyclic carbenes: simultaneous enhancement of reactivity and enantioselectivity in the asymmetric hydroacylation of cyclopropenes.Enantioconvergent synthesis of functionalized γ-butyrolactones via (3 + 2)-annulation.N-Heterocyclic carbene-catalyzed enantioselective annulations: a dual activation strategy for a formal [4+2] addition for dihydrocoumarins.Late-stage diversification of chiral N-heterocyclic-carbene precatalysts for enantioselective homoenolate additions.Diversity-oriented synthesis of drug-like macrocyclic scaffolds using an orthogonal organo- and metal catalysis strategy.Cooperative Lewis acid/N-heterocyclic carbene catalysisExploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations.Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.N-heterocyclic carbene (NHC) complexes of group 4 transition metals.Enantioselective cooperative catalysis.Switchable divergent asymmetric synthesis via organocatalysis.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediatesCatalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactonesOxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from EnalsEnantioselective annulations for dihydroquinolones by in situ generation of azolium enolatesRegio- and stereoselective synthesis of benzothiazolo-pyrimidinones via an NHC-catalyzed Mannich/lactamization domino reaction.N-heterocyclic-carbene-catalyzed synthesis of 2-aryl indoles.A tandem isomerization/prins strategy: iridium(III)/Brønsted acid cooperative catalysisN-Heterocyclic carbene/Brønsted acid cooperative catalysis as a powerful tool in organic synthesis.Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.An N-heterocyclic carbene/Lewis acid strategy for the stereoselective synthesis of spirooxindole lactones.N-heterocyclic carbene-catalyzed conjugate additions of alcohols.N-heterocyclic carbene-catalyzed rearrangements of vinyl sulfones.N-Heterocyclic Carbene-Promoted Rauhut]Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes.NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.N-heterocyclic carbene catalyzed [4+2] cycloaddition of nitroalkenes with oxodienes.N-heterocyclic carbene catalyzed annulation of benzofuran-2,3-diones and enals: a concise synthesis of spiro-bis-lactone.Kinetic resolution of tertiary alcohols: highly enantioselective access to 3-hydroxy-3-substituted oxindoles.Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis.N-heterocyclic carbene-catalyzed double acylation of enones with benzils.Insights into N-Heterocyclic Carbene-Catalyzed [4+2] Annulation Reaction of Enals with Nitroalkenes: Mechanisms, Origin of Chemo- and Stereoselectivity, and Role of Catalyst.Control of N-Heterocyclic Carbene Catalyzed Reactions of Enals: Asymmetric Synthesis of Oxindole-γ-Amino Acid Derivatives.N-Heterocyclic Carbene Catalyzed [3+2] Cycloaddition of Enals with Masked Cinnamates for the Asymmetric One-Pot Synthesis of Adipic Acid Derivatives.
P2860
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P2860
Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Cooperative N-heterocyclic car ...... n reactions with homoenolates.
@en
type
label
Cooperative N-heterocyclic car ...... n reactions with homoenolates.
@en
prefLabel
Cooperative N-heterocyclic car ...... n reactions with homoenolates.
@en
P2860
P356
P1476
Cooperative N-heterocyclic car ...... n reactions with homoenolates.
@en
P2093
Benoit Cardinal-David
Dustin E A Raup
P2860
P304
P356
10.1021/JA910666N
P407
P577
2010-04-01T00:00:00Z