Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling - Wikidata - wikimedia - TriplyDB

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

http://www.wikidata.org/entity/Q37625730

about

Carbohydrates as enantioinduction components in stereoselective catalysis Highly regio- and enantioselective multiple oxy- and amino-functionalizations of alkenes by modular cascade biocatalysis Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement.Protecting group-free, selective cross-coupling of alkyltrifluoroborates with borylated aryl bromides via photoredox/nickel dual catalysis.Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis.Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.Enantiospecific Alkynylation of Alkylboronic Esters.A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates.Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures.Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes.Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.Enantioselective γ-borylation of unsaturated amides and stereoretentive Suzuki-Miyaura cross-coupling.Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesis Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation Regio- and Stereoselective Homologation of 1,2-Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3-Diols and Sch 725674 Hydroxyl-directed stereoselective diboration of alkenes.Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes.Selective uni- and bidirectional homologation of diborylmethane.C(sp3)-C(sp2) cross-coupling of alkylsilicates with borylated aryl bromides - an iterative platform to alkylated aryl- and heteroaryl boronates Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest.Diastereo- and enantioselective reactions of bis(pinacolato)diboron, 1,3-enynes, and aldehydes catalyzed by an easily accessible bisphosphine-Cu complex.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Preparation and Reactivity of Acyclic Chiral Allylzinc Species by a Zinc-Brook Rearrangement.Iterative reactions of transient boronic acids enable sequential C-C bond formation.Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis.Copper-catalyzed asymmetric three-component borylstannation: enantioselective formation of C-Sn bond.Facile Access to Unprecedented Electron-Precise Monohydrodiboranes(4), cis-1,2-Dihydrodiboranes(4), and a 1,1-Dihydrodiborane(5).Highly Enantioselective Allylation of Ketones: An Efficient Approach to All Stereoisomers of Tertiary Homoallylic Alcohols.Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes.Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.Copper-Catalyzed Alkynylboration of Alkenes with Diboron Reagents and Bromoalkynes.Tandem Chemoselective Suzuki-Miyaura Cross-Coupling Enabled by Nucleophile Speciation Control.Highly selective Markovnikov hydroboration of alkyl-substituted terminal alkenes with a phosphine-copper(i) catalyst.One-pot borylation/Suzuki-Miyaura sp2-sp3 cross-coupling.Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines.Alkali metal mediated C-C bond coupling reaction.Practical, efficient, and broadly applicable synthesis of readily differentiable vicinal diboronate compounds by catalytic three-component reactions.

P2860

Q28072011-505B5BA3-1A0A-473D-B1C0-589D1AF5DE32 Q28829942-51223560-9F25-4934-806C-0862C0C53564 Q33749691-BA96F445-4CD4-40E3-BC4C-B6C61C071C84 Q33904991-5B8BAE5C-1894-4C9B-8F22-469A913A2ADE Q35775577-C0162AD3-48AD-4140-8016-9CFC71F5F02E Q37019352-262F9342-EC19-47F6-A5EF-41408BBF6C5A Q39105672-5ADDF998-42F5-4A0B-BA03-126F07033C22 Q39243859-2CCD087C-8FFD-4BF7-961B-23DBB47A8834 Q39397811-5B3DA2BA-702B-4A3C-AC3E-3FB8296AC044 Q39628761-B091E31C-9DD5-4A51-902D-709F85AF3B28 Q39898304-76757830-75AF-4A1C-8EB8-624DB99DB825 Q40499084-7AF396F0-20D9-4EA5-B235-A5E34FA48D15 Q40950916-134569D0-BC6D-4184-ADE3-2D1D2443A23C Q41041595-081D5A2C-06DE-4CCA-85EF-89FC855612AC Q41205919-F68FB68B-A843-44EB-8547-E5B5F141A0A8 Q41527801-48B528E4-BB70-414C-BC4F-DBB430892E22 Q41772288-5D5C213A-CFC0-40E0-84C2-F040338D8CD3 Q41897117-F5637861-3C56-4D72-BAB9-D3B2549B3BE7 Q42142551-14ECEDC7-4D2D-46D5-B7D6-E2E6945AB36A Q42293064-27BCC4B0-3D43-405B-8490-09FADFBA2F94 Q42316230-1CF9B160-8633-4E70-BCA0-3ACAB1783D84 Q42364680-06A5B89F-7AFA-43A5-B2AF-9196F77DF413 Q42738491-2196A31C-49DE-4DF6-8E9D-B98A531A0A15 Q42828017-B14D3D93-D405-4878-9DC9-2166C597E4C2 Q42933893-07631E2E-B9CC-4130-9E05-329B3C217C30 Q46566555-DDCBF31D-8EBC-4389-BAE0-C46840F1B03D Q46575961-EF3606ED-D21F-400F-AD33-19D21DA46622 Q46712091-6AF01CC0-ABC1-4E24-8743-D083C7306519 Q46773283-1F4121DD-C814-4A20-BE90-3098AB9FE0EE Q48170730-DFB95828-10C8-4D25-BD79-51A93B6CCC18 Q48258038-9E9B89A0-D411-45CF-AC40-A33A3BF76AD7 Q48334146-CCF323B9-5694-4DFD-9920-703C4A1F49B3 Q48357236-C6A79541-BE85-4E73-A65E-08BFFBA65CD1 Q49829633-AA98181B-B0B1-436B-B356-46B627BA25B8 Q50957941-C3E41324-C81A-4F1F-92AF-B5F62E1BB46B Q51444957-E7729717-95C3-46ED-A709-BF2A3F834117 Q53120950-8971A19C-2C8E-4DCF-B340-907B2F9D4275 Q53171658-69CA7B4A-DB4E-4B6D-91CC-92DFBF2660D5 Q53608696-5428521A-C2AB-41C0-A971-019EF73709CF Q55396981-6798EFA6-298C-4084-9796-55661A94A7A6

P2860

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

http://www.wikidata.org/entity/Q37625730

description

article científic

@ca

article scientifique

@fr

articolo scientifico

@it

artigo científico

@pt

bilimsel makale

@tr

scientific article published on 18 December 2013

@en

vedecký článok

@sk

vetenskaplig artikel

@sv

videnskabelig artikel

@da

vědecký článek

@cs

name

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

@en

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling.

@nl

type

label

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

@en

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling.

@nl

prefLabel

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

@en

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling.

@nl

P1433

Q37625730-40E7F0AD-DB44-43A9-A92F-FD0B8D396D55

P1476

Q37625730-CB25D70F-A6E1-4492-8E73-30E347B88F85

P2093

Q37625730-16D86C7B-A2A6-4454-B76B-18C0F7E5EFE1

Q37625730-2CD7D61D-A1F6-40C3-B0F2-55101C0F26FC

Q37625730-48372C34-9560-4155-9CC2-3620EACA9600

P2860

Q37625730-01D4C233-6B96-4AEC-BBF5-8D71C5586FFF

Q37625730-170094F2-B874-47B2-99FC-51A864568ECA

Q37625730-1816AF68-91EE-4E0E-99F0-BE15DFD1EF27

Q37625730-197D9318-809C-4E0D-A217-71FC066B12A2

Q37625730-2E821876-82A9-4532-B7A7-2F69EEAFA66B

Q37625730-3066885E-9BB3-439E-A655-1E9EEF8A55D0

Q37625730-35D06525-B699-4588-B2AF-7A3535D4F64A

Q37625730-63433FB5-BE8E-46B2-AEA2-8FD4B35C1D15

Q37625730-94653F37-DDD4-4669-BD28-5B05045E0B67

Q37625730-99684E5B-3E46-441C-A847-D7DECB79D6D9

P2888

Q37625730-D3643183-F51B-426B-893E-661388AB74E2

P304

Q37625730-69D9F611-8E55-40FE-9996-3DB4A3D96A4A

P31

Q37625730-3B85EFDF-33EB-428E-906E-3DC67FE61181

P356

Q37625730-1FDD0B1B-1D08-4835-B50D-354466F10B5C

P407

Q37625730-383FB3CB-F91A-446B-B7FA-419040FFFFE2

P433

Q37625730-3E1FD398-6262-4A18-9321-658F477E76C7

P478

Q37625730-DE1D184E-42CF-498A-8D87-00C8722839D8

P577

Q37625730-5B363FC7-7CC8-41B4-93D7-8B73C8571DC8

P5875

Q37625730-726FC3EB-AFE2-4707-B3DA-EA9C3E5381C4

P6179

Q37625730-AAEB48D6-5E60-4AAC-B20F-0DA43C83A8E8

P698

Q37625730-EC2C2333-8BFA-4223-A686-9122855FD7AD

P932

Q37625730-7F49DC90-9F57-4B87-87E1-F5DE386B1488

P356

P1433

P1476

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

@en

P2093

Christopher H Schuster

http://www.w3.org/2001/XMLSchema#string

James P Morken

http://www.w3.org/2001/XMLSchema#string

Scott N Mlynarski

http://www.w3.org/2001/XMLSchema#string

P2860

Kinetic data for the transmetalation/reductive elimination in palladium-catalyzed Suzuki-Miyaura reactions: unexpected triple role of hydroxide ions used as base.

Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry.

Alkylboranes in the Suzuki-Miyaura Coupling: Stereochemical and Mechanistic Studies.

Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners

Simple organic molecules as catalysts for enantioselective synthesis of amines and alcohols

Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes.

Direct stereospecific amination of alkyl and aryl pinacol boronates.

Scope and mechanism of the Pt-catalyzed enantioselective diboration of monosubstituted alkenes

Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions.

Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.

P2888

P304

386-390

http://www.w3.org/2001/XMLSchema#string

P31

scholarly article

P356

10.1038/NATURE12781

http://www.w3.org/2001/XMLSchema#string

P407

P433

7483

http://www.w3.org/2001/XMLSchema#string

P478

505

http://www.w3.org/2001/XMLSchema#string

P577

2013-12-18T00:00:00Z

http://www.w3.org/2001/XMLSchema#dateTime

P5875

259386993

http://www.w3.org/2001/XMLSchema#string

P6179

1033678084

http://www.w3.org/2001/XMLSchema#string

P698

24352229

http://www.w3.org/2001/XMLSchema#string

P932

3947102

http://www.w3.org/2001/XMLSchema#string