Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
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Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence.Stereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides.Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: stereospecific formation of diarylalkanes and triarylmethanes.Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric SynthesisCross-coupling of mesylated phenol derivatives with potassium ammonio- and amidomethyltrifluoroboratesEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bondsγ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-couplingSynthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl CompoundsAddressing challenges in palladium-catalyzed cross-coupling reactions through ligand design.Copper-catalyzed β-boration of α,β-unsaturated carbonyl compounds with tetrahydroxydiboranePinene-derived iminodiacetic acid (PIDA): a powerful ligand for stereoselective synthesis and iterative cross-coupling of C(sp3) boronate building blocks.Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.Mechanistic Insights into Carbonyl-Directed Rhodium-Catalyzed Hydroboration: ab Initio Study of a Cyclic γ,δ-Unsaturated Amide.Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.The Use of Tertiary Alkylmagnesium Nucleophiles in Ni-Catalyzed Cross-Coupling Reactions.A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates.Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.Palladium-catalyzed allylic substitution with (η6-arene-CH2Z)Cr(CO)(3)-based nucleophiles.Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures.Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: preparation and use of 4-trifluoroboratotetrahydroisoquinolones.Enantioselective γ-borylation of unsaturated amides and stereoretentive Suzuki-Miyaura cross-coupling.Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds.Alkynyl Moiety for Triggering 1,2-Metallate Shifts: Enantiospecific sp2 -sp3 Coupling of Boronic Esters with p-Arylacetylenes.Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling.Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.Nickel-catalyzed cross couplings of benzylic ammonium salts and boronic acids: stereospecific formation of diarylethanes via C-N bond activation.Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl AziridinesNonracemic allylic boronates through enantiotopic-group-selective cross-coupling of geminal bis(boronates) and vinyl halides.Retention or inversion in stereospecific nickel-catalyzed cross-coupling of benzylic carbamates with arylboronic esters: control of absolute stereochemistry with an achiral catalyst.A General, Simple Catalyst for Enantiospecific Cross Couplings of Benzylic Ammonium Triflates and Boronic Acids: No Phosphine Ligand RequiredSelective uni- and bidirectional homologation of diborylmethane.Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp(3)-sp(2) Cross-Coupling.Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters.Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides.
P2860
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P2860
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@en
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@nl
type
label
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@en
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@nl
prefLabel
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@en
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@nl
P2093
P2860
P356
P1476
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
@en
P2093
Cheng-yi Chen
Deidre L Sandrock
Ludivine Jean-Gérard
Spencer D Dreher
P2860
P304
17108-17110
P356
10.1021/JA108949W
P407
P577
2010-11-15T00:00:00Z