Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
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Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion.Enantioselective nucleophile-catalyzed synthesis of tertiary alkyl fluorides via the α-fluorination of ketenes: synthetic and mechanistic studies.How cinchona alkaloid-derived primary amines control asymmetric electrophilic fluorination of cyclic ketones.Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.An in situ directing group strategy for chiral anion phase-transfer fluorination of allylic alcoholsA polycomponent metal-catalyzed aliphatic, allylic, and benzylic fluorination.Catalytic enantioselective cyclization and C3-fluorination of polyenes.Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines.Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes.Catalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones.Enantioselective organocatalytic synthesis of fluorinated molecules.Low-loading asymmetric organocatalysis.Transition metal catalysis and nucleophilic fluorination.The influence of fluorine in asymmetric catalysis.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.Ruthenium-catalyzed C-C coupling of fluorinated alcohols with allenes: dehydrogenation at the energetic limit of β-hydride elimination.Barbier-type anti-Diastereo- and Enantioselective Synthesis of β-Trimethylsilyl, Fluorinated Methyl, Phenylthio Homoallylic Alcohols.Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N3 amideThe development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.From bifunctional to trifunctional (tricomponent nucleophile-transition metal-lewis acid) catalysis: the catalytic, enantioselective α-fluorination of acid chloridesConsecutive iridium catalyzed C-C and C-H bond forming hydrogenations for the diastereo- and enantioselective synthesis of syn-3-fluoro-1-alcohols: C-H (2-fluoro)allylation of primary alcohols.Stereoselective synthesis of fluoroalkenoates and fluorinated isoxazolidinones: N-substituents governing the dual reactivity of nitrones.An efficient route to chiral N-heterocycles bearing a C-F stereogenic center via asymmetric hydrogenation of fluorinated isoquinolines.Chemo- and Stereoselective Cross Rauhut-Currier-Type Reaction of Tri-substituted Alkenes Containing Trifluoromethyl Groups.Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.Selective Synthesis of Fluorine-Containing Cyclic β-Amino Acid Scaffolds.Ethylene glycol: a powerful catalyst-free medium for C-C bond-forming reactions.Organocatalytic asymmetric synthesis of 3-difluoroalkyl 3-hydroxyoxindoles.A diastereoselective Mannich-type reaction of α-fluorinated carboxylate esters: synthesis of β-amino acids containing α-quaternary fluorinated carbon centers.Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.Asymmetric Michael addition of α-fluoro-α-nitroalkanes to nitroolefins: facile preparation of fluorinated amines and tetrahydropyrimidines.Oxidative enantioselective α-fluorination of aliphatic aldehydes enabled by N-heterocyclic carbene catalysis.N-trifluoromethylthiophthalimide: a stable electrophilic SCF3 -reagent and its application in the catalytic asymmetric trifluoromethylsulfenylation.Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source.Pd-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols via capture of active tautomers.Highly stereoselective construction of adjacent tetrasubstituted carbon stereogenic centres via an organocatalytic Mukaiyama-aldol reaction of monofluorinated silyl enol ethers to isatinsA Chiron approach towards the stereoselective synthesis of polyfluorinated carbohydrates
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Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 16 October 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
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Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
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Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
@en
Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
@nl
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Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
@en
Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
@nl
P2093
P2860
P356
P1476
Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?
@en
P2093
Dominique Cahard
Samuel Couve-Bonnaire
P2860
P304
P356
10.1039/B909566G
P577
2009-10-16T00:00:00Z