Enantioselective organocatalytic synthesis of fluorinated molecules.
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Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion.The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Enantioselective nucleophile-catalyzed synthesis of tertiary alkyl fluorides via the α-fluorination of ketenes: synthetic and mechanistic studies.How cinchona alkaloid-derived primary amines control asymmetric electrophilic fluorination of cyclic ketones.An in situ directing group strategy for chiral anion phase-transfer fluorination of allylic alcoholsSyntheses and Applications of (Thio)Urea-Containing Chiral Quaternary Ammonium Salt Catalysts.An organocatalytic strategy for the stereoselective synthesis of C-galactosides with fluorine at the pseudoanomeric carbonCatalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones.Low-loading asymmetric organocatalysis.Hypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.Recent Progress Toward the Synthesis of Trifluoromethyl- and Difluoromethyl-Substituted Cyclopropanes.Asymmetric 18F-fluorination for applications in positron emission tomography.Chiral phase-transfer catalysis in the asymmetric α-heterofunctionalization of prochiral nucleophilesWaste as catalyst: tandem Wittig/conjugate reduction sequence to α-CF3 γ-keto esters that uses Ph3PO as catalyst for the chemoselective conjugate reduction.Highly enantioselective decarboxylative Mannich reaction of malonic acid half oxyesters with cyclic trifluoromethyl ketimines: synthesis of β-amino esters and anti-HIV drug DPC 083.Quinine-thiourea catalyzed enantioselective hydrophosphonylation of trifluoromethyl 2(1H)-quinazolinones.Hydrogen-bond-directed enantioselective decarboxylative Mannich reaction of β-ketoacids with ketimines: application to the synthesis of anti-HIV drug DPC 083.Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.A novel catalytic process for trifluoromethylation of bromoaromatic compounds.Enantioselective electrophilic cyanation of β-keto amides catalysed by a cinchona organocatalyst.The asymmetric synthesis of CF3- or -CF2-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst.Chemo- and Stereoselective Cross Rauhut-Currier-Type Reaction of Tri-substituted Alkenes Containing Trifluoromethyl Groups.An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin.Michael Addition Catalyzed by Chiral Secondary Amine Phosphoramide Using Fluorinated Silyl Enol Ethers: Formation of Quaternary Carbon Stereocenters.Ethylene glycol: a powerful catalyst-free medium for C-C bond-forming reactions.Organocatalytic asymmetric synthesis of 3-difluoroalkyl 3-hydroxyoxindoles.A diastereoselective Mannich-type reaction of α-fluorinated carboxylate esters: synthesis of β-amino acids containing α-quaternary fluorinated carbon centers.The enantioselective addition of 1-fluoro-1-nitro(phenylsulfonyl)methane to isatin-derived ketimines.Palladium-catalyzed intermolecular oxidative cyclization of N-aryl enamines with isocyanides through double sp(2) C-H bonds cleavage: facile synthesis of 4-aminoquinoline derivatives.The direct electrophilic cyanation of β-keto esters and amides with cyano benziodoxole.Asymmetric Michael addition of α-fluoro-α-nitroalkanes to nitroolefins: facile preparation of fluorinated amines and tetrahydropyrimidines.Oxidative enantioselective α-fluorination of aliphatic aldehydes enabled by N-heterocyclic carbene catalysis.N-trifluoromethylthiophthalimide: a stable electrophilic SCF3 -reagent and its application in the catalytic asymmetric trifluoromethylsulfenylation.Highly stereoselective construction of adjacent tetrasubstituted carbon stereogenic centres via an organocatalytic Mukaiyama-aldol reaction of monofluorinated silyl enol ethers to isatins
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P2860
Enantioselective organocatalytic synthesis of fluorinated molecules.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 17 January 2011
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Enantioselective organocatalytic synthesis of fluorinated molecules.
@en
Enantioselective organocatalytic synthesis of fluorinated molecules.
@nl
type
label
Enantioselective organocatalytic synthesis of fluorinated molecules.
@en
Enantioselective organocatalytic synthesis of fluorinated molecules.
@nl
prefLabel
Enantioselective organocatalytic synthesis of fluorinated molecules.
@en
Enantioselective organocatalytic synthesis of fluorinated molecules.
@nl
P2093
P2860
P50
P356
P1476
Enantioselective organocatalytic synthesis of fluorinated molecules
@en
P2093
Guillem Valero
Ramon Rios
Xavier Companyó
P2860
P304
P356
10.1002/CHEM.201001546
P407
P577
2011-01-17T00:00:00Z