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RECENT SYNTHETIC DEVELOPMENTS AND APPLICATIONS OF THE ULLMANN REACTION. A REVIEWMechanistic studies of copper(I)-catalyzed 1,3-halogen migrationEfficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.CuO hollow nanosphere-catalyzed cross-coupling of aryl iodides with thiolsDirect arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I).Transition metal-catalyzed N-arylations of amidines and guanidines.High-valent organometallic copper and palladium in catalysis.Beyond click chemistry - supramolecular interactions of 1,2,3-triazoles.Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development.Chemistry. Copper's contribution to amination catalysis.Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration.Synthesis, characterisation and reactivity of copper(I) amide complexes and studies on their role in the modified Ullmann amination reaction.Synthesis of Substituted 2,2'-Dinitrobiphenyls by a Novel Solvent-Free High Yielding Ullmann Coupling Biarylation.Discriminating role of bases in diketonate copper(I)-catalyzed C-O couplings: phenol versus diarylether.Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles.Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands. Evidence for the Reaction of Iodoarenes With Ligated Anionic CuI Intermediates.A CuI/CuIII prototypical organometallic mechanism for the deactivation of an active pincer-like CuI catalyst in Ullmann-type couplings.Picolinamides as effective ligands for copper-catalysed aryl ether formation: structure-activity relationships, substrate scope and mechanistic investigations.Copper-catalyzed arylation of nitrogen heterocycles from anilines under ligand-free conditions.Possible intermediates of Cu(phen)-catalyzed C-O cross-coupling of phenol with an aryl bromide by in situ ESI-MS and EPR studies.Micro/milliflow processing with selective catalyst microwave heating in the Cu-catalyzed Ullmann etherification reaction: a μ(2)-process.Model Macrocyclic Ligands for Proof-of-Concept Mechanistic Studies in Transition-Metal Catalysis.The synthesis of substituted amino[2.2]paracyclophanes.Synthesis of 2,3'-spirobi[indolin]-2-ones enabled by a tandem nucleophilic benzylation/C(sp2)-N cross-coupling reaction sequence.A Copper-Based Metal-Organic Framework as an Efficient and Reusable Heterogeneous Catalyst for Ullmann and Goldberg Type C-N Coupling Reactions.Palladium-catalyzed intramolecular reductive cross-coupling of Csp2-Csp3 bond formation.Evidence of Cu(I)/Cu(II) Redox Process by X-ray Absorption and EPR Spectroscopy: Direct Synthesis of Dihydrofurans from β-Ketocarbonyl Derivatives and Olefins.A simple access to N-(un)substituted isoquinolin-1(2H)-ones: unusual formation of regioisomeric isoquinolin-1(4H)-ones.Homolytic cleavage of the O-Cu(ii) bond: XAFS and EPR spectroscopy evidence for one electron reduction of Cu(ii) to Cu(i).Ambient-light-mediated copper-catalyzed C-C and C-N bond formation.New Cu-based catalysts supported on TiO2 films for Ullmann S(N)Ar-type C-O coupling reactions.Aryl-O reductive elimination from reaction of well-defined aryl-Cu(III) species with phenolates: the importance of ligand reactivity.Synthesis of indole-annulated sulfur heterocycles using copper-catalysed C–N coupling and palladium-catalysed direct arylationCuI-Catalyzed: One-Pot Synthesis of Diaryl Disulfides from Aryl Halides and Carbon Disulfide2,5-Diamide-Substituted Five-Membered Heterocycles: Challenging Molecular SynthonsThe role of organometallic copper(iii) complexes in homogeneous catalysis
P2860
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P2860
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh
2010年學術文章
@zh-hant
name
The mechanism of the modified Ullmann reaction.
@en
The mechanism of the modified Ullmann reaction.
@nl
type
label
The mechanism of the modified Ullmann reaction.
@en
The mechanism of the modified Ullmann reaction.
@nl
prefLabel
The mechanism of the modified Ullmann reaction.
@en
The mechanism of the modified Ullmann reaction.
@nl
P2093
P356
P1433
P1476
The mechanism of the modified Ullmann reaction.
@en
P2093
Elena Sperotto
Gerard P M van Klink
Gerard van Koten
Johannes G de Vries
P304
10338-10351
P356
10.1039/C0DT00674B
P407
P577
2010-11-01T00:00:00Z