Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent.
about
Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysisDecarboxylative fluorination strategies for accessing medicinally- relevant productsThe Halogen BondThe productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparationCopper-catalyzed trifluoromethylation of unactivated olefinsPd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions.Difluorocarbene-Derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic ElectrophilesResolution of oligomeric species during the aggregation of Aβ1-40 using (19)F NMR.Isolation and Reactivity of Trifluoromethyl Iodonium Salts.Trifluoromethyl ethers--synthesis and properties of an unusual substituent.Chemistry of polyvalent iodine.When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl HalidesShelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions.Enantioselective organocatalytic synthesis of fluorinated molecules.Recent developments on the trifluoromethylation of (hetero)arenes.Introduction of fluorine and fluorine-containing functional groups.Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 2: aldol, Mannich addition reactions, deracemization and (S) to (R) interconversion of α-amino acids.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Trifluoromethylthiolation of aryl iodides and bromides enabled by a bench-stable and easy-to-recover dinuclear palladium(i) catalyst.Direct C-H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis.Probing the interactions of an acyl carrier protein domain from the 6-deoxyerythronolide B synthase.Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3H-1λ(3),2-benziodaoxol-3-one.Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters.Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale.Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Nickel-catalyzed trifluoromethylthiolation of Csp2-O bonds.Enantioselective α-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis.2'-SCF3 uridine-a powerful label for probing structure and function of RNA by 19F NMR spectroscopy.Iron-catalyzed cyclopropanation with trifluoroethylamine hydrochloride and olefins in aqueous media: in situ generation of trifluoromethyl diazomethane.Efficient access to extended Yagupolskii-Umemoto-type reagents: triflic acid catalyzed intramolecular cyclization of ortho-ethynylaryltrifluoromethylsulfanes.Base-catalyzed electrophilic trifluoromethylthiolation of terminal alkynes.Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Copper-boxmi complexes as highly enantioselective catalysts for electrophilic trifluoromethylthiolations.
P2860
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P2860
Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent.
description
2007 nî lūn-bûn
@nan
2007 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Mild electrophilic trifluorome ...... philes by a hypervalent iodine
@nl
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@ast
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@en
type
label
Mild electrophilic trifluorome ...... philes by a hypervalent iodine
@nl
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@ast
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@en
prefLabel
Mild electrophilic trifluorome ...... philes by a hypervalent iodine
@nl
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@ast
Mild electrophilic trifluorome ...... alent iodine(III)-CF3 reagent.
@en
P356
P1476
Mild electrophilic trifluorome ...... valent iodine(III)-CF3 reagent
@en
P2093
Iris Kieltsch
Patrick Eisenberger
P304
P356
10.1002/ANIE.200603497
P407
P577
2007-01-01T00:00:00Z