about
Proton-hydride tautomerism in hydrogen evolution catalysisCombination of Scanning Probe Microscopy and Coordination Chemistry: Structural and Electronic Study of Bis(methylbenzimidazolyl)ketone and Its Iron ComplexAcceptorless dehydrogenation and dehydrogenative coupling of alcohols catalysed by protic NHC ruthenium complexes.General low-temperature reaction pathway from precursors to monomers before nucleation of compound semiconductor nanocrystals.Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen BondingTriaminoborane-bridged diphosphine complexes with Ni and Pd: coordination chemistry, structures, and ligand-centered reactivity.Non-symmetrical, potentially redox non-innocent imino NHC pyridine 'pincers' via a zinc ion template-assisted synthesis.A square-planar osmium(ii) complex.Functional group migrations between boron and metal centres within transition metal-borane and -boryl complexes and cleavage of H-H, E-H and E-E' bonds.Mechanistic Insights and Computational Design of Transition-Metal Catalysts for Hydrogenation and Dehydrogenation Reactions.Nickel pincer model of the active site of lactate racemase involves ligand participation in hydride transfer.Development of Proton-Responsive Catalysts.Designing effective 'frustrated Lewis pair' hydrogenation catalysts.Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.Synthesis of a sterically bulky diphosphine synthon and Ru(ii) complexes of a cooperative tridentate enamide-diphosphine ligand platform.Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium and interconversion reactivity.Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles.Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex.The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity.Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal→Borane Interaction.Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts.Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex.Phosphine-imine and -enamido ligands for acceptorless dehydrogenation catalysis.Synthesis, structure and reactivity of Pd and Ir complexes based on new lutidine-derived NHC/phosphine mixed pincer ligands.Mechanisms for dehydrogenation and hydrogenation of N-heterocycles using PNP-pincer-supported iron catalysts: a density functional study.A Hemilabile and Cooperative N-Donor-Functionalized 1,2,3-Triazol-5-Ylidene Ligand for Alkyne Hydrothiolation Reactions.Metal-Ligand Cooperativity in a Methandiide-Derived Iridium Carbene Complex.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.Zero-valent isocyanides of nickel, palladium and platinum as transition metal σ-type Lewis bases.Carbon-Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex.A DFT study unveils the secret of how H2 is activated in the N-formylation of amines with CO2 and H2 catalyzed by Ru(ii) pincer complexes in the absence of exogenous additives.Catalytic (de)hydrogenation promoted by non-precious metals - Co, Fe and Mn: recent advances in an emerging field.Formation of Palladium η2 -Bound Chalcogenoketones across a Pd+ -C- Bond.Cationic PCP iridaepoxide and carbene complexes for facile water elimination and activation processes.Metal-ligand cooperation at tethered π-ligands.Insights into the enhanced Ce[triple bond, length as m-dash]N triple bond in the HCe[triple bond, length as m-dash]N molecule.NNP-Type Pincer Imidazolylphosphine Ruthenium Complexes: Efficient Base-Free Hydrogenation of Aromatic and Aliphatic Nitriles under Mild Conditions.A ruthenium(ii) bis(phosphinophosphinine) complex as a precatalyst for transfer-hydrogenation and hydrogen-borrowing reactions.Protic N-Heterocyclic Carbene Versus Pyrazole: Rigorous Comparison of Proton- and Electron-Donating Abilities in a Pincer-Type Framework.Cobalt Pincer Complexes for Catalytic Reduction of Carboxylic Acid Esters.
P2860
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P2860
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
2015年论文
@zh
2015年论文
@zh-cn
name
Metal-ligand cooperation.
@en
type
label
Metal-ligand cooperation.
@en
prefLabel
Metal-ligand cooperation.
@en
P356
P1476
Metal-ligand cooperation.
@en
P304
12236-12273
P356
10.1002/ANIE.201503873
P407
P577
2015-09-07T00:00:00Z