Regio- and stereoselective Ni-catalyzed 1,4-hydroboration of 1,3-dienes: access to stereodefined (Z)-allylboron reagents and derived allylic alcohols.
about
The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisSynthesis of (+)-discodermolide by catalytic stereoselective borylation reactions.Axial preferences in allylations via the Zimmerman-Traxler transition state.γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.Biosynthesis and chemical synthesis of presilphiperfolanol natural products.Diastereocontrol in asymmetric allyl-allyl cross-coupling: stereocontrolled reaction of prochiral allylboronates with prochiral allyl chlorides.Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis.Direct ruthenium-catalyzed C-C coupling of ethanol: diene hydro-hydroxyethylation to form all-carbon quaternary centers.Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.Remarkable levels of enantioswitching in catalytic asymmetric hydroboration.The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complexEnantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights.Amplification of anti-diastereoselectivity via Curtin-Hammett effects in ruthenium-catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes: diastereoselective formation of all-carbon quaternary centers.Allylation of nitrosobenzene with pinacol allylboronates. A regioselective complement to peroxide oxidation.Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy estersEnantioselective carbocycle formation through intramolecular Pd-catalyzed allyl-aryl cross-coupling.Deuteration of boranes: catalysed versus non-catalysed processes.Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones.Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.Cross-metathesis/isomerization/allylboration sequence for a diastereoselective synthesis of anti-homoallylic alcohols from allylbenzene derivatives and aldehydes.Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes.
P2860
Q33763459-B43C7147-84B7-4A9C-BEDE-019E846310DFQ34228288-3E126251-60CA-41DD-B71C-E45462CB72CAQ35744687-00F3A64B-40FF-46A9-93A0-DB780BB96E1AQ36697087-82B0BE9F-319F-4AF7-837C-687C1A4728F3Q38207567-0DECE18A-3E92-4BD6-B02A-16C36F746FE7Q39190422-FBBFB272-3304-4F9F-8154-9E1F488EED2BQ40581007-C223BA15-E569-4802-A3A6-6BF1059F9C52Q40998694-ED745E34-CCCC-467D-801F-8E719AFA791BQ41087897-F727D4BC-F66A-4152-AC26-EB3E101B171FQ41846280-F01835F1-23A8-4054-931F-F332C2A0A0A5Q41849452-1C1497A7-F65F-49ED-9255-FC0601AF5D8BQ41853595-8A63BB7C-5308-4293-96C8-C9384BACFAA3Q41865909-089F30D0-FA93-45B8-B75A-43F6A0EE8EA9Q41966233-44FBC75C-C769-430B-AEC6-9BDF9D327A77Q42464168-3F1ADD97-CBC6-45DE-AD41-5565ECD5E0DDQ42588665-FD7C6B66-E699-4B5A-87E6-7FA1FCEEE544Q42803961-3E6F8AB7-2AF5-4F04-9968-98474C02656DQ46055571-793165F2-4718-4EEC-8322-D5D726A98C3AQ48225582-90E7D9F1-BA9C-4C15-AD09-5C9B70549BB3Q48354015-25EF77AB-B9DF-4D78-AA4B-080AEFD03BCCQ51054703-64F89A88-02D9-44F7-8B60-56AA21640A59Q55620821-021D83F5-3587-4921-9CAF-F7769B38456E
P2860
Regio- and stereoselective Ni-catalyzed 1,4-hydroboration of 1,3-dienes: access to stereodefined (Z)-allylboron reagents and derived allylic alcohols.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Regio- and stereoselective Ni- ...... and derived allylic alcohols.
@en
type
label
Regio- and stereoselective Ni- ...... and derived allylic alcohols.
@en
prefLabel
Regio- and stereoselective Ni- ...... and derived allylic alcohols.
@en
P2860
P356
P1476
Regio- and stereoselective Ni- ...... and derived allylic alcohols.
@en
P2093
James P Morken
Robert J Ely
P2860
P304
P356
10.1021/JA910750B
P407
P577
2010-03-01T00:00:00Z