One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcohols.
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Cooperativity of regiochemistry control strategies in reductive couplings of propargyl alcohols and aldehydesOne-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcoholsOverriding Felkin control: a general method for highly diastereoselective chelation-controlled additions to alpha-silyloxy aldehydes.Highly diastereoselective chelation-controlled additions to α-silyloxy ketones.Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols.Practical catalytic asymmetric synthesis of diaryl-, aryl heteroaryl-, and diheteroarylmethanols.Regio- and stereoselective Ni-catalyzed 1,4-hydroboration of 1,3-dienes: access to stereodefined (Z)-allylboron reagents and derived allylic alcohols.A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Diastereoselective chelation-controlled additions to β-silyloxy aldehydes.Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.Pd-catalyzed orthogonal Knoevenagel/Perkin condensation-decarboxylation-Heck/Suzuki sequences: tandem transformations of benzaldehydes into hydroxy-functionalized antidiabetic stilbene-cinnamoyl hybrids and asymmetric distyrylbenzenes.One-pot zinc-promoted asymmetric alkynylation/brook-type rearrangement/ene-allene cyclization: highly selective formation of three new bonds and two stereocenters in acyclic systems.
P2860
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P2860
One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcohols.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on June 2009
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
One-pot multicomponent couplin ...... isubstituted allylic alcohols.
@en
One-pot multicomponent couplin ...... diastereo- and enantioenriched
@nl
type
label
One-pot multicomponent couplin ...... isubstituted allylic alcohols.
@en
One-pot multicomponent couplin ...... diastereo- and enantioenriched
@nl
prefLabel
One-pot multicomponent couplin ...... isubstituted allylic alcohols.
@en
One-pot multicomponent couplin ...... diastereo- and enantioenriched
@nl
P2093
P2860
P356
P1476
One-pot multicomponent couplin ...... isubstituted allylic alcohols.
@en
P2093
Luca Salvi
Michael H Kerrigan
Patrick J Carroll
Patrick J Walsh
Sang-Jin Jeon
Young K Chen
P2860
P304
P356
10.1021/JA809821X
P407
P577
2009-06-01T00:00:00Z