Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
about
Radicals: Reactive Intermediates with Translational PotentialCatalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Highly Enantioselective Oxidation of Nonactivated Aliphatic C-H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes.Setting Cyclohexane Stereochemistry with Oxidation.Copper-catalyzed cyanothiolation to incorporate a sulfur-substituted quaternary carbon center.Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation.Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage.Copper-catalyzed regioselective 1,2-thioamidation of alkenes.Rhodium-Catalyzed Enantioselective Radical Addition of CX4 Reagents to Olefins.Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes.Radical asymmetric intramolecular α-cyclopropanation of aldehydes towards bicyclo[3.1.0]hexanes containing vicinal all-carbon quaternary stereocenters.Enantioselective cyclizations and cyclization cascades of samarium ketyl radicals.Radical Enantioselective C(sp3 )-H Functionalization.Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes.Reversing the Regioselectivity of Halofunctionalization Reactions through Cooperative Photoredox and Copper Catalysis.Highly Enantioselective α-Cyanation with 4-Acetylphenyl Cyanate.Facile synthesis of cyanofurans via Michael-addition/cyclization of ene-yne-ketones with trimethylsilyl cyanide.Photoinduced, copper-catalyzed three components cyanofluoroalkylation of alkenes with fluoroalkyl iodides as fluoroalkylation reagents.Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp3)-H bonds.Radikalische enantioselektive C(sp3)-H-FunktionalisierungAsymmetric remote C-H borylation of internal alkenes via alkene isomerization
P2860
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P2860
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
description
2016 nî lūn-bûn
@nan
2016年の論文
@ja
2016年論文
@yue
2016年論文
@zh-hant
2016年論文
@zh-hk
2016年論文
@zh-mo
2016年論文
@zh-tw
2016年论文
@wuu
2016年论文
@zh
2016年论文
@zh-cn
name
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
@en
type
label
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
@en
prefLabel
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
@en
P2093
P2860
P356
P1433
P1476
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
@en
P2093
Dinghai Wang
Guosheng Liu
Pinhong Chen
Scott D McCann
Shannon S Stahl
P2860
P304
P356
10.1126/SCIENCE.AAF7783
P407
P577
2016-09-01T00:00:00Z