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Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (L11(AuCl)), 933752 (L12(AuCl)a), 933753 (L9(AuCl)), 933754 (L10(AuCl)), 933756 (L8(AuCl)), 933757 (L12(AGuanine binding to gold nanoparticles through nonbonding interactions.Gold-catalyzed Intermolecular [4C + 3C] Cycloaddition Reactions.Bimetallic reductive elimination from dinuclear Pd(III) complexes.A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.Development of catalysts and ligands for enantioselective gold catalysisPhosphoramidite gold(I)-catalyzed diastereo- and enantioselective synthesis of 3,4-substituted pyrrolidinesMechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Tandem Cycloisomerization/Suzuki Coupling of Arylethynyl MIDA BoronatesMechanism of gold(I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment.Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl esters[3,3]-Sigmatropic rearrangement versus carbene formation in gold-catalyzed transformations of alkynyl aryl sulfoxides: mechanistic studies and expanded reaction scopeGold-Catalyzed Intramolecular Cyclizations of Cyclopropenes with Propargylic Esters.Total synthesis of (+)-sieboldine a: evolution of a pinacol-terminated cyclization strategy.Gold(I) Carbenoids: On-Demand Access to Gold(I) Carbenes in SolutionSynthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.When cyclopropenes meet gold catalysts.Recent developments in gold-catalyzed cycloaddition reactions.Intriguing mechanistic labyrinths in gold(I) catalysis.Gold(I)-catalyzed enantioselective cycloaddition reactions.Gold-catalyzed rearrangements and beyond.Characterization of vinylgold intermediates: gold-mediated cyclization of acetylenic amides.A non-diazo approach to α-oxo gold carbenes via gold-catalyzed alkyne oxidation.Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition.New Approaches to the Synthesis of Metal Carbenes.Recent Advances in Gold-Catalyzed Intermolecular Aryl C-H Functionalization.Recent Developments in Coinage Metal Catalyzed Transformations of Stabilized Vinyldiazo Compounds: Beyond Carbenic Pathways.Gold-Catalyzed Enantioselective Annulations.Gold-catalyzed Intermolecular Oxidations of 2-Ketonyl-1-ethynyl Benzenes with N-Hydoxyanilines to Yield 2-Aminoindenones via Gold Carbene Intermediates.Overriding the alkynophilicity of gold: catalytic pathways from higher energy Au(I)-substrate complexes and reactant deactivation via unproductive complexation in the gold(I)-catalyzed propargyl Claisen rearrangement.Gold Catalysed Redox Synthesis of Imidazo[1,2-a]pyridine using Pyridine N-Oxide and Alkynes.Mechanism of C-F reductive elimination from palladium(IV) fluorides.Quantitative assessment of the carbocation/carbene character of the gold-carbene bond.Enantioselective cyclizations of silyloxyenynes catalyzed by cationic metal phosphine complexes.Gold(I)-catalyzed enantioselective polycyclization reactions.Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.On the impact of steric and electronic properties of ligands on gold(I)-catalyzed cycloaddition reactions.
P2860
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P2860
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
A bonding model for gold(I) carbene complexes.
@en
type
label
A bonding model for gold(I) carbene complexes.
@en
prefLabel
A bonding model for gold(I) carbene complexes.
@en
P2093
P2860
P50
P356
P1433
P1476
A bonding model for gold(I) carbene complexes
@en
P2093
Diego Benitez
Nathan D Shapiro
William A Goddard
P2860
P2888
P304
P356
10.1038/NCHEM.331
P577
2009-09-01T00:00:00Z