Mechanism of C-F reductive elimination from palladium(IV) fluorides.
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Catalysis for fluorination and trifluoromethylationLate-Stage Fluorination: From Fundamentals to ApplicationRadiofluorination of a pre-formed gallium(III) aza-macrocyclic complex: towards next-generation positron emission tomography (PET) imaging agents.Application of palladium-mediated (18)F-fluorination to PET radiotracer development: overcoming hurdles to translation.Bimetallic reductive elimination from dinuclear Pd(III) complexes.On the mechanism of palladium-catalyzed aromatic C-H oxidationPalladium(III) in Synthesis and Catalysis.A fluoride-derived electrophilic late-stage fluorination reagent for PET imaging.Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.C-H bond activation at palladium(IV) centers.Access to novel fluorovinylidene ligands via exploitation of outer-sphere electrophilic fluorination: new insights into C-F bond formation and activation.Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactorEvidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.Palladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides.Catalytic enantioselective cyclization and C3-fluorination of polyenes.An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Transition metal catalysis and nucleophilic fluorination.High-valent organometallic copper and palladium in catalysis.18F labeling of arenes.Introduction of fluorine and fluorine-containing functional groups.Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV.Late-stage formation of carbon-fluorine bonds.Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.Site-selective Suzuki-Miyaura coupling of heteroaryl halides - understanding the trends for pharmaceutically important classes.Heterocycle Formation via Palladium-Catalyzed C-H Functionalization.Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids.Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR3)2(CO)(H)2]: predicted scope and regioselectivities.Palladium-catalyzed directing group-assisted C8-triflation of naphthalenes.Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluorideTuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment.Electrophilic fluorination of cationic Pt-aryl complexesOxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex.C-F Bond Formation for the Synthesis of Aryl Fluorides.Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible.Pd-catalyzed C-H fluorination with nucleophilic fluoride.Palladium(III)-catalyzed fluorination of arylboronic acid derivatives.
P2860
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P2860
Mechanism of C-F reductive elimination from palladium(IV) fluorides.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh
2010年學術文章
@zh-hant
name
Mechanism of C-F reductive elimination from palladium
@nl
Mechanism of C-F reductive elimination from palladium(IV) fluorides.
@en
type
label
Mechanism of C-F reductive elimination from palladium
@nl
Mechanism of C-F reductive elimination from palladium(IV) fluorides.
@en
prefLabel
Mechanism of C-F reductive elimination from palladium
@nl
Mechanism of C-F reductive elimination from palladium(IV) fluorides.
@en
P2093
P2860
P356
P1476
Mechanism of C-F reductive elimination from palladium(IV) fluorides.
@en
P2093
Alexandra E Strom
Diego Benitez
Pingping Tang
Takeru Furuya
Tobias Ritter
William A Goddard
P2860
P304
P356
10.1021/JA909371T
P407
P577
2010-03-01T00:00:00Z