Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
about
Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush"Development of an automated microfluidic reaction platform for multidimensional screening: reaction discovery employing bicyclo[3.2.1]octanoid scaffolds.Gold-catalyzed Intermolecular [4C + 3C] Cycloaddition Reactions.Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors.A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.Gold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.Recent advances in the gold-catalyzed additions to C-C multiple bonds.Mechanistic studies on Au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.Recent developments in gold-catalyzed cycloaddition reactions.New Approaches to the Synthesis of Metal Carbenes.Gold-catalyzed efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation.Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Gold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketalsGold-catalyzed [3+3]-annulation of azomethine imines with propargyl esters.Construction of 2,3-dihydrofuran cores through the [3+2] cycloaddition of gold alpha-carbonylcarbenoids with alkenes.Gold(I)-catalyzed enantioselective synthesis of benzopyrans via rearrangement of allylic oxonium intermediates.Asymmetric synthesis of medium-sized rings by intramolecular Au(I)-catalyzed cyclopropanation.Gold carbene or carbenoid: is there a difference?Gold carbenes from substituted propargyl acetates: intramolecular ene-type reactions to 2-acetoxynaphthalene derivatives.In situ generation of nucleophilic allenes by the gold-catalyzed rearrangement of propargylic esters for the highly diastereoselective formation of intermolecular C(sp3)-C(sp2) bonds.Reactivity of stabilized vinyl diazo derivatives toward unsaturated hydrocarbons: regioselective gold-catalyzed carbon-carbon bond formation.Gold-catalyzed sequential activation of propargylic carboxylates: a facile route to benzoannulenes.Oxazepine synthesis by copper-catalyzed intermolecular cascade reactions between O-propargylic oximes and dipolarophiles.Gold-catalyzed cycloaddition reactions of ethyl diazoacetate, nitrosoarenes, and vinyldiazo carbonyl compounds: synthesis of isoxazolidine and benzo[b]azepine derivatives.Mild rhodium(III)-catalyzed cyclization of amides with α,β-unsaturated aldehydes and ketones to azepinones: application to the synthesis of the homoprotoberberine framework.[5+2] Cycloaddition of 2-(2-Aminoethyl)oxiranes with Alkynes via Epoxide Ring-Opening: A Facile Access to Azepines.Rhodium(I)-Catalyzed Intermolecular Aza-[4+3] Cycloaddition of Vinyl Aziridines and Dienes: Atom-Economical Synthesis of Enantiomerically Enriched Functionalized Azepines.Rationalization of the selectivity between 1,3- and 1,2-migration: a DFT study on gold(i)-catalyzed propargylic ester rearrangement.Ruthenium-Catalyzed C-C Bond Cleavage of 2H-Azirines: A Formal [3+2+2] Cycloaddition to Fused Azepine Skeletons.Hexafluoroantimonic acid catalysis: formal [3+2+2] cycloaddition of aziridines with two alkynes.Rhenium-Catalyzed Annulation ReactionsIntermolecular and Regioselective Access to Polysubstituted Benzo- and Dihydrobenzo[c]azepine Derivatives: Modulating the Reactivity of Group 6 Non-Heteroatom-Stabilized Alkynyl Carbene Complexes
P2860
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P2860
Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
@en
type
label
Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
@en
prefLabel
Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
@en
P2860
P356
P1476
Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.
@en
P2093
Nathan D Shapiro
P2860
P304
P356
10.1021/JA803890T
P407
P577
2008-06-25T00:00:00Z