Ruthenium-catalyzed cyclopropanation of alkenes using propargylic carboxylates as precursors of vinylcarbenoids.
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Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush"Recent applications of the divinylcyclopropane-cycloheptadiene rearrangement in organic synthesisGold-catalyzed Intermolecular [4C + 3C] Cycloaddition Reactions.A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.A Stimuli-Responsive Rotaxane-Gold Catalyst: Regulation of Activity and Diastereoselectivity.Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach.Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphatesLigand effects in homogeneous Au catalysis.Ruthenium Vinyl Carbene Intermediates in Enyne Metathesis.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.Recent developments in gold-catalyzed cycloaddition reactions.The use of Br/Cl to promote regioselective gold-catalyzed rearrangement of propargylic carboxylates: an efficient synthesis of (1Z, 3E)-1-bromo/chloro-2-carboxy-1,3-dienes.New Approaches to the Synthesis of Metal Carbenes.Fluorenes and styrenes by Au(I)-catalyzed annulation of enynes and alkynesSubstituent Effect on the Formation and Their Reactivity of Platinum Carbenoids.Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migrationGold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketalsGold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions.Interception of a Rautenstrauch intermediate by alkynes for [5+2] cycloaddition: rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9-diynes to bicyclo[5.3.0]decatrienes.Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters.Electronic effects in the pt-catalyzed cycloisomerization of propargylic esters: synthesis of 2,3-disubstituted indolizines as a mechanistic probe.Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones.Synthesis of highly functionalized cyclohexenone rings: rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition.High chemoselectivity in the phenol synthesis.Rhodium- and platinum-catalyzed [4+3] cycloaddition with concomitant indole annulation: synthesis of cyclohepta[b]indoles.Rhenium(I)-catalyzed cyclization of silyl enol ethers containing a propargyl carboxylate moiety: versatile access to highly substituted phenols.Gold(I)-catalyzed enantioselective synthesis of benzopyrans via rearrangement of allylic oxonium intermediates.Synthesis of phenanthrenes and polycyclic heteroarenes by transition-metal catalyzed cycloisomerization reactions.Carene terpenoids by gold-catalyzed cycloisomerization reactions.Gold(I)-catalyzed divergence in the preparation of bicyclic enol esters: from exclusively [3C+2C]-cycloaddition reactions to exclusive formation of vinylcyclopropanes.Oxazepine synthesis by copper-catalyzed intermolecular cascade reactions between O-propargylic oximes and dipolarophiles.Transition-metal-catalyzed divergent functionalization of [60]fullerene with propargylic esters.The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes.Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,4,9-Dienyne Esters to 3 a,6-Methanoisoindole Esters with Pro-Inflammatory Cytokine Antagonist Activity.Gold-catalyzed cycloisomerization of 1,6,8-dienyne carbonates and esters to cis-cyclohepta-4,8-diene-fused pyrrolidines.Pd-Catalyzed oxidative isomerization of propargylic acetates: highly efficient access to α-acetoxyenones via alkenyl Csp(2)-O bond-forming reductive elimination from Pd(IV).
P2860
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P2860
Ruthenium-catalyzed cyclopropanation of alkenes using propargylic carboxylates as precursors of vinylcarbenoids.
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh-hant
name
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@en
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@nl
type
label
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@en
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@nl
prefLabel
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@en
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@nl
P2093
P356
P1476
Ruthenium-catalyzed cyclopropa ...... precursors of vinylcarbenoids.
@en
P2093
Kouichi Ohe
Sakae Uemura
P304
P356
10.1021/JO034841A
P407
P577
2003-10-01T00:00:00Z