Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover.
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Quinone-Catalyzed Selective Oxidation of Organic MoleculesA survey of sulfide ligands for allylic C-H oxidations of terminal olefins.Palladium-catalyzed regioselective azidation of allylic C-H bonds under atmospheric pressure of dioxygen.Allylic functionalization of unactivated olefins with Grignard reagents.Non-Directed Allylic C-H Acetoxylation in the Presence of Lewis Basic Heterocycles.Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions.Wacker-type oxidation of internal alkenes using Pd(Quinox) and TBHPThe Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification.Palladium-catalyzed oxidative carbocyclizations.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.Sequential catalysis for stereoselective synthesis of complex polyketides.Cross-dehydrogenative coupling for the intermolecular C-O bond formation.Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols.Coordination chemistry and applications of versatile 4,5-diazafluorene derivatives.Synthesis of esters via sp(3) C-H functionalisation.Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition.Molecular ligand modulation of palladium nanocatalysts for highly efficient and robust heterogeneous oxidation of cyclohexenone to phenol.Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions.Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions.Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes.Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst().Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction.Alternative pathways for Heck intermediates: palladium-catalyzed oxyarylation of homoallylic alcoholsA C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins.O2-Promoted Allylic Acetoxylation of Alkenes: Assessment of "Push" vs. "Pull" Mechanisms and Comparison between O2 and Benzoquinone.Palladium Catalyzed Aryl C-H Amination with O2 via In Situ Formation of Peroxide-Based Oxidant(s) from Dioxane.Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes.Primary alcohols from terminal olefins: formal anti-Markovnikov hydration via triple relay catalysis.Palladium(II)-catalyzed allylic C-H oxidation of hindered substrates featuring tunable selectivity over extent of oxidation.Detection of Palladium(I) in Aerobic Oxidation Catalysis.Palladium-catalyzed aerobic intermolecular cyclization of acrylic acid with 1-octene to afford α-methylene-γ-butyrolactones: the remarkable effect of continuous water removal from the reaction mixture and analysis of the reaction by kinetic, ESI-MS,Palladium-Catalyzed [3+3] Annulation between Diarylamines and α,β-Unsaturated Acids through CH Activation: Direct Access to 4-Substituted 2-Quinolinones.The development of copper-catalyzed aerobic oxidative coupling of H-tetrazoles with boronic acids and an insight into the reaction mechanism.Developing Neolignans as Proangiogenic Agents: Stereoselective Total Syntheses and Preliminary Biological Evaluations of the Four Guaiacylglycerol 8-O-4'-Coniferyl Ethers.
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P2860
Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Allylic C-H acetoxylation with ...... ve aerobic catalytic turnover.
@en
type
label
Allylic C-H acetoxylation with ...... ve aerobic catalytic turnover.
@en
prefLabel
Allylic C-H acetoxylation with ...... ve aerobic catalytic turnover.
@en
P2093
P2860
P356
P1476
Allylic C-H acetoxylation with ...... ve aerobic catalytic turnover.
@en
P2093
Alison N Campbell
Ilia A Guzei
Paul B White
Shannon S Stahl
P2860
P304
15116-15119
P356
10.1021/JA105829T
P407
P577
2010-11-01T00:00:00Z