Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant.
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Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical IndustryBis(dibenzylideneacetone)palladium(0)Enantioselective construction of remote quaternary stereocentresSelective catalytic oxidation of glycerol to dihydroxyacetone.Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes.Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2First ketene cycloaddition approach to (±)-junionone.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.Cross-coupling in flow.Challenges in modelling homogeneous catalysis: new answers from ab initio molecular dynamics to the controversy over the Wacker process.Reaction of O2 with [(-)-sparteine]Pd(H)Cl: evidence for an intramolecular [H-L]+ "reductive elimination" pathway.Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones.Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols.Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols.Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents.High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NO x Mediators: Implications for Fuel Cells and Aerobic Oxidation CatalysisA reactor for high-throughput high-pressure nuclear magnetic resonance spectroscopy.Wacker Oxidation of Terminal Alkenes Over ZrO2 -Supported Pd Nanoparticles Under Acid- and Cocatalyst-Free Conditions.Molecular ligand modulation of palladium nanocatalysts for highly efficient and robust heterogeneous oxidation of cyclohexenone to phenol.Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions.Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air.Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions.Asymmetric palladium-catalyzed hydroarylation of styrenes and dienesAllylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover.Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity.Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite.Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst().Synthesis of 2-Alkynoates by Palladium(II)-Catalyzed Oxidative Carbonylation of Terminal Alkynes and Alcohols.Palladium(II)-Catalysed Aminocarbonylation of Terminal Alkynes for the Synthesis of 2-Ynamides: Addressing the Challenges of Solvents and Gas Mixtures.Catalytic asymmetric synthesis of chiral allylic esters.Development of Safe and Scalable Continuous-Flow Methods for Palladium-Catalyzed Aerobic Oxidation Reactions.Palladium-catalyzed 1,1-aryloxygenation of terminal olefins.Metal-catalyzed cycloetherification reactions of β,γ- and γ,δ-allendiols: chemo-, regio-, and stereocontrol in the synthesis of oxacycles.O2-Promoted Allylic Acetoxylation of Alkenes: Assessment of "Push" vs. "Pull" Mechanisms and Comparison between O2 and Benzoquinone.Palladium Catalyzed Aryl C-H Amination with O2 via In Situ Formation of Peroxide-Based Oxidant(s) from Dioxane.Synthesis and X-ray characterization of novel palladium(II) complexes with tunable chiral anionic counterions.Recyclable Mitsunobu reagents: catalytic Mitsunobu reactions with an iron catalyst and atmospheric oxygen.Aldehyde-selective Wacker-type oxidation of unbiased alkenes enabled by a nitrite co-catalyst.
P2860
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P2860
Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
Recent advancements and challe ...... ar oxygen as the sole oxidant.
@en
type
label
Recent advancements and challe ...... ar oxygen as the sole oxidant.
@en
prefLabel
Recent advancements and challe ...... ar oxygen as the sole oxidant.
@en
P2860
P356
P1476
Recent advancements and challe ...... ar oxygen as the sole oxidant.
@en
P2093
Keith M Gligorich
Matthew S Sigman
P2860
P304
P356
10.1039/B902868D
P407
P577
2009-05-14T00:00:00Z