Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.

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NHC-Organocatalyzed CAr -O Bond Cleavage: Mild Access to 2-Hydroxybenzophenones.Exploring Cooperative Effects in Oxidative NHC Catalysis: Regioselective Acylation of Carbohydrates.NHC-organokatalysierte CAr -O-Bindungsspaltung: milder Zugang zu 2-Hydroxybenzophenonen

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P2860

Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.

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Rate and Equilibrium Constants ...... markable 2-Substituent Effect.

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Rate and Equilibrium Constants ...... markable 2-Substituent Effect.

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Rate and Equilibrium Constants ...... markable 2-Substituent Effect.

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Rate and Equilibrium Constants ...... markable 2-Substituent Effect.

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Rate and Equilibrium Constants ...... markable 2-Substituent Effect.

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Andrew D Smith

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AnnMarie C O'Donoghue

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Christopher J Collett

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James E Taylor

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Oliver R Maguire

http://www.w3.org/2001/XMLSchema#string

Richard S Massey

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P2860

Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)

The Catalytic Asymmetric Intramolecular Stetter Reaction.

Discovering New Reactions with N-Heterocyclic Carbene Catalysis.

Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step

Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction.

Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.

Organocatalysis by N-heterocyclic carbenes.

Organocatalytic umpolung: N-heterocyclic carbenes and beyond.

A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.

The effect of the N-mesityl group in NHC-catalyzed reactions.

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6991-6996

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scholarly article

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10.1002/ANGE.201501840

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127

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Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.

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P2860

P2860

Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.

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