The effect of the N-mesityl group in NHC-catalyzed reactions.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesChiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.Cooperative Lewis acid/N-heterocyclic carbene catalysisOxyanion steering and CH-π interactions as key elements in an N-heterocyclic carbene-catalyzed [4 + 2] cycloaddition.A Computational Study of the Origin of Stereoinduction in NHC-Catalyzed Annulation Reactions of α,β-Unsaturated Acyl Azoliums.Catalytic selective synthesis.A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts.NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones.Enantioselective N-heterocyclic carbene catalyzed annulation reactions with imidazolidinones.Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes.NHC-catalyzed hydroacylation of styrenes.Diaminocyclopropenylidene organocatalysts: beyond N-heterocyclic carbenes.Characterization of the key intermediates of carbene-catalyzed umpolung by NMR spectroscopy and X-ray diffraction: breslow intermediates, homoenolates, and azolium enolates.The catalytic versatility of low toxicity dialkyltriazolium salts: in situ modification facilitates diametrically opposed catalysis modes in one pot.N-heterocyclic carbene-catalyzed highly enantioselective synthesis of substituted dihydropyranopyrazolones.N-tert-butyl triazolylidenes: catalysts for the enantioselective (3+2) annulation of α,β-unsaturated acyl azoliums.N-heterocyclic carbene-catalyzed double acylation of enones with benzils.N-Heterocyclic carbene catalysed redox isomerisation of esters to functionalised benzaldehydes.N-Heterocyclic carbene-catalyzed sulfa-Michael addition of enals.Carboranes as Aryl Mimetics in Catalysis: A Highly Active Zwitterionic NHC-Precatalyst.NHC-Organocatalyzed CAr -O Bond Cleavage: Mild Access to 2-Hydroxybenzophenones.Direct NHC-catalysed redox amidation using CO2 for traceless masking of amine nucleophiles.Carbene-catalyzed LUMO activation of alkyne esters for access to functional pyridines.Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes.Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst.N-Heterocyclic carbene-catalyzed formal cross-coupling reaction of α-haloenals with thiols: organocatalytic construction of sp2 carbon-sulfur bonds.Umpolung reactions in an ionic liquid catalyzed by electrogenerated N-heterocyclic carbenes. Synthesis of saturated esters from activated α,β-unsaturated aldehydes.N-Heterocyclic carbene-catalyzed stereoselective construction of olefinic carbon-sulfur bonds via cross-coupling reaction of gem-difluoroalkenes and thiols.Conjugate umpolung of β,β-disubstituted enals by dual catalysis with an N-heterocyclic carbene and a Brønsted acid: facile construction of contiguous quaternary stereocenters.NHC-organokatalysierte CAr -O-Bindungsspaltung: milder Zugang zu 2-HydroxybenzophenonenProton transfer reactions ofN-aryl triazolium salts: unusualortho-substituent effectsMechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent
P2860
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P2860
The effect of the N-mesityl group in NHC-catalyzed reactions.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
The effect of the N-mesityl group in NHC-catalyzed reactions.
@en
type
label
The effect of the N-mesityl group in NHC-catalyzed reactions.
@en
prefLabel
The effect of the N-mesityl group in NHC-catalyzed reactions.
@en
P2860
P356
P1433
P1476
The effect of the N-mesityl group in NHC-catalyzed reactions.
@en
P2093
Jeffrey W Bode
Jessada Mahatthananchai
P2860
P304
P356
10.1039/C1SC00397F
P577
2012-01-01T00:00:00Z