about
Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experimentAgostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes.C-H bond activation in transition metal species from a computational perspective.η(6) -Arene-Zirconium-PNP-Pincer Complexes: Mechanism of Their Hydrogenolytic Formation and Their Reactivity as Zirconium(II) Synthons.Deciphering Selectivity in Organic Reactions: A Multifaceted Problem.Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium-Assisted Multicomponent Reactions.Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes.DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)-H activation: role of the nature of the base and the phosphine.Synthesis, structure, and reductive elimination in the series Tp'Rh(PR3)(Ar(F))H; determination of rhodium-carbon bond energies of fluoroaryl substituents.Intramolecular palladium-catalyzed alkane C-H arylation from aryl chlorides.M=N(alpha) cycloaddition and N(alpha)-N(beta) insertion in the reactions of titanium hydrazido compounds with alkynes: a combined experimental and computational study.Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes.Synthesis, bonding and reactivity of a terminal titanium alkylidene hydrazido compound.PGSE and NOE NMR evidence for higher order aggregation in some cationic ruthenium complexes in both protic and aprotic solvents.Biscarbene-ruthenium complexes in catalysis: novel stereoselective synthesis of (1E,3E)-1,4-disubstituted-1,3-dienes via head-to-head coupling of terminal alkynes and addition of carboxylic acids.Defluorination of perfluoropropene using Cp*2ZrH2 and Cp2ZrHF: a mechanism investigation from a joint experimental-theoretical perspective.Is the allylpalladium structure altered between solid and solutions?Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion.Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations.Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups: method and mechanistic study.A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release.Beta-H transfer from the metallacyclobutane: a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst.Synthesis of a ruthenium bis(diisopropylamino(isocyano)borane) complex from the activation of an amino(cyano)borane.Syntheses, reactivity and DFT studies of group 2 and group 12 metal complexes of tris(pyrazolyl)methanides featuring "free" pyramidal carbanions.Dimethylaminoborane (H2BNMe2) coordination to late transition metal centers: snapshots of the B-H oxidative addition process.Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization.A mechanochemical approach to access the proline-proline diketopiperazine framework.An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.Structure and reactivity of trans-bis[2-(2-chloroethyl)pyridine]palladium chloride (1). A study on the elimination reaction of 1 and 2-(2-chloroethyl)pyridine induced by quinuclidine in acetonitrile.Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations.Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications.New Scandium Borylimido Chemistry: Synthesis, Bonding, and Reactivity.New Titanium Borylimido Compounds: Synthesis, Structure, and Bonding.Mild Decarboxylative C-H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold.Isolation and structural characterization of a titanacyclopropane as key intermediate in the double aryl Grignard addition to 2-(arylethynyl)pyridine derivatives.A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization of Amine-Boranes to Cyclic Boranes under Mild Conditions.Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.Reactions of Titanium Hydrazides with Silanes and Boranes: N-N Bond Cleavage and N Atom Functionalization.Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates: Ti=N(α) cycloaddition, Ti=N(α) insertion and N(α) -N(β) bond cleavage.
P50
Q35758469-3FD85EA6-9C65-4DDB-A341-2BC430657865Q35758667-CF300366-14CD-4B1E-B48D-7C716B90EDD5Q37672585-1CAF2CCD-E351-4546-8EB0-9C4B15A7F3FDQ39711862-0EB3BCF7-7343-4693-BF08-1F10695DF009Q39789016-31FFD17C-BA6A-44D7-A0A1-9D6AC2B13341Q40214044-D2B1604E-C522-4ED7-9487-0A957911393FQ42866094-6123F4D4-E137-4AD7-B570-16ABEFC917C7Q42867775-CF1D7B2B-CC9F-449B-86C7-3B5CD5DCB39BQ42868988-50805BF8-F9E2-4BD6-AA39-172A82ED06B3Q42948149-25C450ED-E677-4947-8435-5C3B983F64B7Q42975108-1F584526-7593-4168-8242-E174FDC5475DQ43585367-47A6AE1D-475E-435A-926C-334BF87B3DE4Q44431613-A57230EE-84B8-40E4-AB48-F309BCAF36B4Q44569846-E4EBD4D1-9B9E-482C-9AD6-F7FA5F95D7A5Q44593549-9116ACB9-9D6B-47BE-90B5-D588DBE2860FQ44868434-13523B14-3FFF-4D29-9FCF-D99E9A64ABF9Q44986339-78071AB3-DBAB-41DE-AFB3-69B81CD68120Q45923554-6B7FF1CA-2848-44F2-9E33-2EF7075470D0Q46005832-A8FD003C-8866-4599-ACF0-77AF7DE84D26Q46312045-0FE2E037-50F7-43E8-A725-EE8AEB27AB34Q46386343-F6AEBDBB-15EA-46FC-B801-D2F014E400D8Q46422247-8666A0A5-35F5-4A92-8A28-DE59AA26E8C7Q46547367-60927146-EE3F-42DF-A590-1A0340788815Q46586567-BDC2D320-5569-4884-A29A-032AE25ABB18Q46711361-52C17B1A-B15A-4BA6-B97D-BB6115B2D8D9Q46712790-3AE3BDA8-58C9-4399-AF93-093537F72778Q46800983-4D8C87D6-188B-4F2D-82FC-6D7FD3DB4B6FQ46803423-804B6AA8-75D7-442E-AE7D-F69131F995CCQ46852024-56495D7E-50E0-4E8F-8CB0-53585FFABBE4Q46865814-A68D1F1D-CEE6-4B48-B5C4-8C9EFC1C2F35Q46978398-5494C226-6A05-4409-9514-CD6DA5206304Q48131767-017E2986-A20B-4ACB-AFF5-CE32CDB7997BQ48182475-DC40B259-1D43-49CF-BC4E-ACEF8F0DDBBDQ48356635-9899D777-E5F1-45F7-8969-37E6307204F8Q50065413-56414719-5A1B-459F-B20E-632868902FD1Q50951016-62E0CEC5-89AE-4D19-B7A2-2A5F420FE60EQ52848729-14130157-3E6A-4A79-AD74-A3B2196F332CQ52927249-3AB005DE-5190-4854-8D5A-4A014D1EF9F0Q53258166-D2AFFCCA-D1DF-493D-B1A7-8BDDA86B163EQ53277842-6A2B8A11-F373-4152-B194-D89EFF8AE892
P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Eric Clot
@ast
Eric Clot
@en
Eric Clot
@es
Eric Clot
@nl
Eric Clot
@sl
type
label
Eric Clot
@ast
Eric Clot
@en
Eric Clot
@es
Eric Clot
@nl
Eric Clot
@sl
prefLabel
Eric Clot
@ast
Eric Clot
@en
Eric Clot
@es
Eric Clot
@nl
Eric Clot
@sl
P1053
P-9585-2015
P106
P21
P31
P3829
P496
0000-0001-8332-5545