An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.
about
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).Stable cyclic carbenes and related species beyond diaminocarbenes.Anion-exchange-triggered 1,3-shift of an NH proton to iridium in protic n-heterocyclic carbenes: hydrogen-bonding and ion-pairing effects.Applications of NMR diffusion methods with emphasis on ion pairing in inorganic chemistry: a mini-review.Importance of the 6'-hydroxy group and its configuration for apramycin activity.Fluorine-decoupled carbon spectroscopy for the determination of configuration at fully substituted, trifluoromethyl- and perfluoroalkyl-bearing carbons: comparison with 19F-1H heteronuclear Overhauser effect spectroscopy.Bis-N-heterocyclic carbene palladium(IV) tetrachloride complexes: synthesis, reactivity, and mechanisms of direct chlorinations and oxidations of organic substrates.Insight into the role of the counteranion of an imidazolium salt in organocatalysis: a combined experimental and computational study.A Capped Octahedral MHC6 Compound of a Platinum Group Metal.Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes.Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction.Sequential Reactions of Alkynes on an Iridium(III) Single Site.Expedient Mechanosynthesis of N,N-Dialkyl Imidazoliums and Silver(I)-Carbene Complexes in a Ball-Mill.Changes in ligating abilities of the singlet and triplet states of normal, abnormal and remote N-heterocyclic carbenes depending on their aromaticities.Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights† †Dedicated to the memory of Paul von R. Schleyer. ‡ ‡Electronic supplementary information (ESI) available: CIF files gi
P2860
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P2860
An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.
description
2005 nî lūn-bûn
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2005年の論文
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2005年学术文章
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2005年学术文章
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2005年学术文章
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2005年学术文章
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name
An anion-dependent switch in s ...... an imidazolium salt with IrH5
@nl
An anion-dependent switch in s ...... azolium salt with IrH5(PPh3)2.
@en
type
label
An anion-dependent switch in s ...... an imidazolium salt with IrH5
@nl
An anion-dependent switch in s ...... azolium salt with IrH5(PPh3)2.
@en
prefLabel
An anion-dependent switch in s ...... an imidazolium salt with IrH5
@nl
An anion-dependent switch in s ...... azolium salt with IrH5(PPh3)2.
@en
P2093
P50
P356
P1476
An anion-dependent switch in s ...... azolium salt with IrH5(PPh3)2.
@en
P2093
Anes Kovacevic
Anthony R Chianese
John R Miecznikowski
Leah N Appelhans
Robert H Crabtree
P304
16299-16311
P356
10.1021/JA055317J
P407
P577
2005-11-01T00:00:00Z