Pyrrole synthesis via allylic sp3 C-H activation of enamines followed by intermolecular coupling with unactivated alkynes.
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A mild and efficient AgSbF6-catalyzed synthesis of fully substituted pyrroles through a sequential propargylation/amination/cycloisomerization reaction.An atom-economic synthesis of nitrogen heterocycles from alkynesExpedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.Multifunctionalized 3-hydroxypyrroles in a three-step, one-pot cascade process from methyl 3-TBSO-2-diazo-3-butenoate and nitrones.Scope and Mechanistic Study of the Coupling Reaction of α, β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling PathwaysDirect Synthesis of Protoberberine Alkaloids by Rh-Catalyzed C-H Bond Activation as the Key Step.Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesA C-H bond activation-based catalytic approach to tetrasubstituted chiral allenesRhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles.Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process.Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascadePractical synthesis of aryl-2-methyl-3-butyn-2-ols from aryl bromides via conventional and decarboxylative copper-free Sonogashira coupling reactionsAmide-directed tandem C-C/C-N bond formation through C-H activation.Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.Direct metal-catalyzed regioselective functionalization of enamides.Associative Covalent Relay: An Oxadiazolone Strategy for Rhodium(III)-Catalyzed Synthesis of Primary Pyridinylamines.Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds.Recent developments in transition metal catalysis for quinazolinone synthesis.Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study.A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation.Direct Synthesis of Highly Substituted Pyrroles and Dihydropyrroles Using Linear Selective Hydroacylation Reactions.Simple two-step synthesis of 2,4-disubstituted pyrroles and 3,5-disubstituted pyrrole-2-carbonitriles from enones.Rhodium(III)-Catalyzed Allylic C(sp(3))-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles.Methyl 3-amino-but-2-enoateLigand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.Rhodium-catalyzed annulation of N-benzoylsulfonamide with isocyanide through C-H activation.Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes.Rhodium catalyzed synthesis of isoindolinones via C-H activation of N-benzoylsulfonamides.Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis.An approach to benzophosphole oxides through silver- or manganese-mediated dehydrogenative annulation involving C-C and C-P bond formation.Cross-coupling/annulations of quinazolones with alkynes for access to fused polycyclic heteroarenes under mild conditions.Direct access to benzo[b]furans through palladium-catalyzed oxidative annulation of phenols and unactivated internal alkynes.Rhodium-catalyzed directed sulfenylation of arene C-H bonds.Aerobic synthesis of pyrroles and dihydropyrroles from imines: palladium(II)-catalyzed intramolecular C-H dehydrogenative cyclization.Rhodium(III)-catalyzed synthesis of cyclopenta[b]pyrroles from 1,2-diketones, 2-aminopyridine, and alkynes.Selective ruthenium-catalyzed three-component synthesis of pyrroles.Rhodium(III)-catalyzed vinylic sp2 C-H bond functionalization: efficient synthesis of pyrido[1,2-α]benzimidazoles and imidazo[1,2-α]pyridines.Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes.
P2860
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P2860
Pyrrole synthesis via allylic sp3 C-H activation of enamines followed by intermolecular coupling with unactivated alkynes.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@en
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@nl
type
label
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@en
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@nl
prefLabel
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@en
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@nl
P356
P1476
Pyrrole synthesis via allylic ...... ling with unactivated alkynes.
@en
P2093
Frederic W Patureau
Souvik Rakshit
P304
P356
10.1021/JA104305S
P407
P577
2010-07-01T00:00:00Z