High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene.
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New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Cations and dications of heavier group 14 elements in low oxidation states.The chemistry of benzodisilacyclobutenes and benzobis(disilacyclobutene)s: new development of transition-metal-catalyzed reactions, stereochemistry and theoretical studies.Open-shell lanthanide(II+) or -(III+) complexes bearing σ-silyl and silylene ligands: synthesis, structure, and bonding analysis.A silyl radical formed by muonium addition to a silylene.Disilicon complexes with two hexacoordinate Si atoms: paddlewheel-shaped isomers with (ClN4 )Si-Si(S4 Cl) and (ClN2 S2 )Si-Si(S2 N2 Cl) skeletons.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.Activation of alkynes by an α-diimine-stabilized Al-Al-bonded compound: insertion into the Al-Al bond or cycloaddition to AlN2C2 rings.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound.The synthesis, structure and reactivity of an imine-stabilized carboranylphosphorus(i) compound.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane.Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity.Bis(amidinato)- and bis(guanidinato)silylenes and silylenes with one sterically demanding amidinato or guanidinato ligand: synthesis and reactivity.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.New insights into small molecule activation by acyclic silylenes: a computational investigation.Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene-zinc iodide adducts.Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.Reaction of an N-heterocyclic carbene-stabilized silicon(II) monohydride with alkynes: [2+2+1] cycloaddition versus hydrogen abstraction.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.Facile access to silicon-functionalized bis-silylene titanium(II) complexes.Mixed valence η6-arene cobalt(I) and cobalt(II) compound.Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si-Si bond cleavage.Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl].Stepwise isolation of an unprecedented silylene supported dinuclear gold(i) cation with aurophilic interaction.On the Reactivity of the Silylene PhC(NtBu)2SiNPh2toward Organic SubstratesFacile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene LigandA début for base stabilized monoalkylsilylenesA Stable Cation of a CSi3P Five-Membered Ring with a Weakly Coordinating Chloride AnionA Stable Cation of a CSi3P Five-Membered Ring with a Weakly Coordinating Chloride AnionZwitterionic Si-C-Si-P and Si-P-Si-P Four-Membered Rings with Two-Coordinate Phosphorus AtomsZwitterionic Si-C-Si-P and Si-P-Si-P Four-Membered Rings with Two-Coordinate Phosphorus AtomsReaction of a Base-Stabilized Bis(silylene) [PhC(NtBu)2Si]2 with Cyclooctatetraene without Cleavage of the Si-Si BondA stable silicon(ii) monohydrideElegant approach to spacer arranged silagermylene and bis(germylene) compoundsPentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble β-diketiminatolead(ii) monofluorideConvenient Access to Monosilicon Epoxides with Pentacoordinate Silicon
P2860
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P2860
High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
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2010年學術文章
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2010年學術文章
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name
High yield access to silylene ...... s of stable disilacyclobutene.
@en
High yield access to silylene RSiCl
@nl
type
label
High yield access to silylene ...... s of stable disilacyclobutene.
@en
High yield access to silylene RSiCl
@nl
prefLabel
High yield access to silylene ...... s of stable disilacyclobutene.
@en
High yield access to silylene RSiCl
@nl
P50
P356
P1476
High yield access to silylene ...... s of stable disilacyclobutene.
@en
P2093
Daniel Stern
Sakya S Sen
P304
P356
10.1021/JA9091374
P407
P577
2010-01-01T00:00:00Z