Synthesis and Characterization of Heterobimetallic Al-O-Cu Complexes toward Models for Heterogeneous Catalysts on Metal Oxide Surfaces.Cr(i)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes.Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols, and Trisilanols.Silicon based radicals, radical ions, diradicals and diradicaloids.An Electrophilic Carbene-Anchored Silylene-Phosphinidene.The Structure of the Carbene Stabilized Si2H2 May Be Equally Well Described with Coordinate Bonds as with Classical Double Bonds.A soluble molecular variant of the semiconducting silicondiselenide.Synthesis and reaction of monomeric germanium(II) and lead(II) dimethylamide and the synthesis of germanium(II) hydrazide by cleavage of one N-H bond of hydrazine.Facile syntheses of silylene nickel carbonyl complexes from Lewis base stabilized chlorosilylenes.Cu24O24Si8R8: organic soluble 56-membered copper(I) siloxane cage and its use in homogeneous catalysis.Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene.Selective aromatic C-F and C-H bond activation with silylenes of different coordinate silicon.A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene.Facile synthesis of dichlorosilane by metathesis reaction and dehydrogenation of dihydrogermane by a frustrated Lewis pair.Reactivity studies of a Ge(I)-Ge(I) compound with and without cleavage of the Ge-Ge bond.Reaction of β-diketiminate tin(II) dimethylamide LSnNMe₂ [L = HC(CMeNAr)₂; Ar = 2,6-iPr₂C₆H₃] with ketones and alkynes.An efficient route for the synthesis of a Tin(II) substituted carbodiimide from a diazo compound.High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene.Synthesis of phosphine substituted beta-diketiminate based isomeric Ge(II) complexes.Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane.Binding of urea and thiourea with a barbiturate derivative: experimental and theoretical approach.Assembling heterometals through oxygen: an efficient way to design homogeneous catalysts.Synthesis and structural characterization of aluminum iminophosphonamide complexes.Hydrostannylation of ketones and alkynes with LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3].Dehydrogenation of LGeH by a Lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C(6)F(5))(3) and trimethylsilyl diazomethane: an unprecedented rearrangement of a diazocompound to an isonitrile.A singlet biradicaloid zinc compound and its nonradical counterpart.Easy access to silicon(0) and silicon(II) compounds.A stable singlet biradicaloid siladicarbene: (L:)2Si.Reactions of AlH(3) x NMe(3) with nitriles: structural characterization and substitution reactions of hexameric aluminum imides.Syntheses, structures, and surface aromaticity of the new carbaalane [(AlH)(6)(AlNMe(3))(2)(CCH(2)R)(6)] (R = Ph, CH(2)SiMe(3)) and a stepwise functionalization of the inner and outer sphere of the cluster.Synthesis and structures of [[HC(CMeNAr)(2)]Ge(S)X] (Ar = 2,6-iPr(2)C(6)H(3), X = F, Cl, Me): structurally characterized examples with a formal double bond between group 14 and 16 elements bearing a halide.Adamantane-like aluminum amide-phosphate from alumazene.[Zn4(thf)(4)(MeZn)(4)(O(3)SiR)(4)] (R=2,6-iPr(2)C(6)H(3)N(SiMe3)), a compound containing trigonal-planar, tetrahedral, and trigonal-bipyramidal metal atoms: a new route to larger aggregates.Neutral and ionic aluminum, gallium, and indium compounds carrying two or three terminal ethynyl groups.Synthesis and structural characterization of a terminal hydroxide containing alumoxane via hydrolysis of aluminum hydrides.Synthesis of carbaalane halogen derivatives.Molecular zinc phosphonates: synthesis and X-ray crystal structures of [[(ZnMe)4(THF)2][tBuPO3]2] and [[(ZnEt)3(Zn(THF))3][tBuPO3]4[mu3-OEt]].A seven-membered aluminum sulfur allenyl heterocycle arising from the conversion of an aluminacyclopropene with CS2.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.Reaction of LAlH2 with tert-butyl hydrogenperoxide under C-H Bond activation and substitution leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound.
P50
Q30974580-5FA91D16-25AB-45FF-BA5B-819DB3C97BB8Q33851586-D30ECE75-4C32-48FD-982A-C90F6947FCE9Q34114410-7EAEBD82-8CE5-4A55-8015-1306C0494D6CQ38639024-7FAE1F11-C065-4539-9EA1-E0EC4F19C11FQ38907423-46BB4528-FC99-47DD-8B8A-E6187D0AB233Q39520464-E31BBE5B-E611-4E4F-A88A-3C96F8D6160BQ40956205-ED2A42AD-E38A-417D-9F38-1BCB8838B495Q42168203-93C42EA1-D63A-4A5A-A428-935D93B5F815Q42865326-A6DA9C1C-37B8-4952-A9BB-74344C3945BCQ42935181-F79CD889-C5E9-407E-A8D6-E05747A2203CQ42973059-12DB9EBF-66D7-45E0-8D42-8AA157410A91Q42979021-FF333578-0052-48E9-A2EC-38F4913195D2Q42979049-3F911005-EADD-473E-A14F-88694C69CA8BQ43045678-9AD1F821-CC58-496C-B5E5-35B7EB5980EEQ43049127-351E4F08-DEF4-467B-8343-27EFC3DF4A85Q43094581-BB621EBD-E5DF-4637-9E01-CDE6E3852249Q43144183-77851996-F84D-4C8E-94E3-DA36AE27F186Q43204169-F79EAD9D-10F5-43B0-A5BE-876F17B1B813Q43214096-44B966C3-3A7B-4E79-8440-1B18310C3327Q43214127-12F7EF3F-4CE3-4DF3-A406-E70028E5E5E9Q43230911-FCBFF9A3-A532-4E9C-9FBF-65D6416D5E18Q43264637-97197A52-5033-435D-B2DE-B6A1C99683C4Q43279250-7699E8CD-52F1-4AFE-93BA-CCBAA2C13325Q43279720-0D23F2B7-F645-4419-8EEF-FB9EDBFAAB3AQ43282548-F8090128-A22F-4FAB-B150-3E3EC030A9BBQ43628155-B0350F1B-0DB7-424D-A500-AC6B97D67413Q43781334-3697685B-C5D7-401C-B120-8CD86FD600F6Q43804857-C257DB52-163E-45AD-97E9-C411181AC9D5Q43972094-DC57D631-0C76-4443-B4D0-07EABF706B85Q43983747-BB526BEB-AA1E-4579-82FA-B001C1CC35A3Q44066228-FC91A060-4DC9-40A0-9273-6C693EBE2675Q44241322-1B41834A-FC96-4C81-8668-5C1D5EB70A0EQ44255366-AD68324E-61B7-49FB-98FC-953725E6E109Q44535100-EB958B50-7878-4666-BAAF-9F98B837BE5AQ44766278-8E9492A1-EC57-44D0-B026-92C3D60A8B97Q44923828-3B6891A9-5374-46D8-9F84-A0DFCEE50860Q44977690-105BE224-560B-4602-BF85-81B8A3D301CDQ45021279-6EEF3D69-1ECB-42AC-BDA5-843306D5C79FQ45114675-C87F192C-B243-4135-8F0D-8509168C7CCAQ45283653-D2F4F212-ABB0-4113-A432-53757C1E3C15
P50
description
Duits scheikundige
@nl
German chemist
@en
German chemist
@en-ca
German chemist
@en-gb
Saksamaa keemik
@et
chimist german
@ro
chimiste allemand
@fr
deutscher Chemiker
@de
kimist gjerman
@sq
professor académico alemão
@pt
name
Herbert W. Roesky
@ca
Herbert W. Roesky
@da
Herbert W. Roesky
@de
Herbert W. Roesky
@en
Herbert W. Roesky
@es
Herbert W. Roesky
@fr
Herbert W. Roesky
@nb
Herbert W. Roesky
@nds
Herbert W. Roesky
@nl
Herbert W. Roesky
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type
label
Herbert W. Roesky
@ca
Herbert W. Roesky
@da
Herbert W. Roesky
@de
Herbert W. Roesky
@en
Herbert W. Roesky
@es
Herbert W. Roesky
@fr
Herbert W. Roesky
@nb
Herbert W. Roesky
@nds
Herbert W. Roesky
@nl
Herbert W. Roesky
@nn
altLabel
Herbert Roesky
@de
Herbert W Roesky
@es
Herbert Walter Roesky
@ro
Roesky
@de
prefLabel
Herbert W. Roesky
@ca
Herbert W. Roesky
@da
Herbert W. Roesky
@de
Herbert W. Roesky
@en
Herbert W. Roesky
@es
Herbert W. Roesky
@fr
Herbert W. Roesky
@nb
Herbert W. Roesky
@nds
Herbert W. Roesky
@nl
Herbert W. Roesky
@nn