C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment.
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Cooperative Reductive Elimination: The Missing Piece in the Oxidative-Coupling Mechanistic Puzzle.Transmetallation versus β-hydride elimination: the role of 1,4-benzoquinone in chelation-controlled arylation reactions with arylboronic acids.Development of Chiral Bis-hydrazone Ligands for the Enantioselective Cross-Coupling Reactions of Aryldimethylsilanolates.γ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine•borane adducts.Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates.Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling reactions.Bimetallic catalysis using transition and Group 11 metals: an emerging tool for C-C coupling and other reactions.The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV.Exceptionally fast carbon-carbon bond reductive elimination from gold(III).Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of PtBu3 and CO on Reductive Elimination.How can theory predict the selectivity of palladium-catalyzed cross-coupling of pristine aromatic molecules?Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperatureCationic Pd(II)-catalyzed C-H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies.Computational study of the Sonogashira cross-coupling reaction in the gas phase and in dichloromethane solution.Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies.Catalyst- and solvent-dependent stereodivergence in the intramolecular Et(2)Zn/Pd(0) -promoted carbonyl propargylation: mechanistic implications.On the regiochemical differences between Pd-catalyzed heterocyclization-allylation and -arylation reactions of alkynylbenzamides: preparation of 4-allyl-isochromen-1-imines and computational study.Stability and Unimolecular Reactivity of Palladate(II) Complexes [Ln PdR3 ](-) (L=Phosphine, R=Organyl, n=0 and 1).Multiple Roles of Isocyanides in Palladium-Catalyzed Imidoylative Couplings: A Mechanistic Study.Palladium(0)/NHC-Catalyzed Reductive Heck Reaction of Enones: A Detailed Mechanistic Study.Addition of C-C and C-H bonds by pincer-iridium complexes: a combined experimental and computational study.Combined DFT and experimental studies of C-C and C-X elimination reactions promoted by a chelating phosphine-alkene ligand: the key role of penta-coordinate Pd(II.).Radical Pd(III)/Pd(I) reductive elimination in palladium sequences.Reductive Eliminations from Diarylpalladium(II) Complexes: A Combined Experimental and Computational Investigation.Promoting Difficult Carbon-Carbon Couplings: Which Ligand Does Best?Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers.Bridging organometallics and quantum chemical topology: Understanding electronic relocalisation during palladium-catalyzed reductive elimination.The molecular mechanism of palladium-catalysed cyanoesterification of methyl cyanoformate onto norbornene.The Transmetalation Process in Suzuki-Miyaura Reactions: Calculations Indicate Lower Barrier via Boronate IntermediateOn the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenesUnderstanding palladium complexes structures and reactivities: beyond classical point of view
P2860
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P2860
C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment.
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2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
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2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
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2009年學術文章
@zh-hant
name
C-C reductive elimination in p ...... study supported by experiment.
@en
C-C reductive elimination in p ...... study supported by experiment.
@nl
type
label
C-C reductive elimination in p ...... study supported by experiment.
@en
C-C reductive elimination in p ...... study supported by experiment.
@nl
prefLabel
C-C reductive elimination in p ...... study supported by experiment.
@en
C-C reductive elimination in p ...... study supported by experiment.
@nl
P2093
P50
P356
P1476
C-C reductive elimination in p ...... study supported by experiment.
@en
P2093
Ataualpa A C Braga
Mónica H Pérez-Temprano
Rosana Alvarez
P304
P356
10.1021/JA808036J
P407
P50
P577
2009-03-01T00:00:00Z