about
Insights into the mechanism of the Negishi reaction: ZnRX versus ZnR2 reagentsPalladium Round Trip in the Negishi Coupling of trans-[PdMeCl(PMePh2)2] with ZnMeCl: An Experimental and DFT Study of the Transmetalation StepThe mechanisms of the Stille reaction.Polymer [Pd(CH2SO2C6H4Me)2]n, a precursor to remarkably stable Pd organometallics.Bimetallic catalysis using transition and Group 11 metals: an emerging tool for C-C coupling and other reactions.Room-temperature columnar mesophases in triazine-gold thiolate metal-organic supramolecular aggregates.Highly fluorescent platinum(II) organometallic complexes of perylene and perylene monoimide, with Pt σ-bonded directly to the perylene core.Photoisomerizable metallomesogens and soft crystals based on orthopalladated complexes.Synthesis and catalytic activity of gold chiral nitrogen acyclic carbenes and gold hydrogen bonded heterocyclic carbenes in cyclopropanation of vinyl arenes and in intramolecular hydroalkoxylation of allenes.A deep tetranuclear metallo-cavitand with bis(aryl) palladium bridges.Liquid-crystalline self-organization of isocyanide-containing dendrimers induced by coordination to gold(I) fragments.Enthalpy of ligand substitution in cis organopalladium complexes with monodentate ligands.C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment.[Pd(Fmes)2(tmeda)]: a case of intermittent C-H···F-C hydrogen-bond interaction in solution.A warning on the use of radical traps as a test for radical mechanisms: they react with palladium hydrido complexes.Binuclear mesogenic copper(i) isocyanide complexes with an unusual inorganic core formed by two tetrahedra sharing an edge.Dinuclear azolato-bridged complexes of the nickel group metals with haloaryl ligands: a reinvestigation of their behavior in solution.Conformational preferences driven by the C-methyl substituent in chelated o-diphenylphosphino-alpha-methyl-N,N-dimethylbenzylamine rhodium complexes.Anionic platinum complexes with 2-pyridylphosphines as ligands for rhodium: synthesis of zwitterionic Pt-Rh organometallic compounds.Dimeric palladium complexes with bridging aryl groups: when are they stable?Stille coupling involving bulky groups feasible with gold cocatalyst.Aryl palladium carbene complexes and carbene-aryl coupling reactions.Luminescent gold(I) metallo-acids and their hydrogen bonded supramolecular liquid crystalline derivatives with decyloxystilbazole as hydrogen acceptor.Gold(I) complexes with hydrogen-bond supported heterocyclic carbenes as active catalysts in reactions of 1,6-enynes.Stannylated polynorbornenes as new reagents for a clean Stille reaction.When are tricoordinated PdII species accessible? Stability trends and mechanistic consequences.Luminescence and mesogenic properties in crown-ether-isocyanide or carbene gold(I) complexes: luminescence in solution, in the solid, in the mesophase, and in the isotropic liquid state.Mechanism of the rhodium-catalyzed asymmetric isomerization of allylamines to enamines.Gold(I)-carbenes derived from 4-pyridylisocyanide complexes: supramolecular macrocycles supported by hydrogen bonds, and luminescent behavior.Luminescent goldI carbenes from 2-pyridylisocyanide complexes: structural consequences of intramolecular versus intermolecular hydrogen-bonding interactions.Mononuclear, dinuclear, and hexanuclear goldI complexes with (aza-15-crown-5)dithiocarbamate.H-Bonded adducts of [2,4,6-{(C10H21O)3C6H2NH}3C3N3] with [LnM{PPh2(C6H4CO2H)}] displaying columnar mesophases at room temperature.The decisive role of ligand metathesis in Au/Pd bimetallic catalysis.Functional isocyanide metal complexes as building blocks for supramolecular materials: hydrogen-bonded liquid crystals.Diamine-catalyzed addition of ZnEt2 to PhC(O)CF3 : two mechanisms and autocatalytic asymmetric enhancement.In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient.Promoting Difficult Carbon-Carbon Couplings: Which Ligand Does Best?Detection and reactivity of a palladium alkoxycarbene.Cyclopalladated complexes of perylene imine: mononuclear complexes with five- or six-membered metallacycles.Dramatic mechanistic switch in Sn/Au(I) group exchanges: transmetalation vs. oxidative addition.
P50
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P50
description
researcher
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wetenschapper
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հետազոտող
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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Pablo Espinet
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P106
P1153
7007019315
P21
P31
P496
0000-0001-8649-239X