beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes.
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Complexes of Bulky β-Diketiminate LigandsIntermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo speciesGeometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex.Bis(μ-oxo) dicopper(III) species of the simplest peralkylated diamine: enhanced reactivity toward exogenous substrates.Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes.Variable character of O-O and M-O bonding in side-on (eta(2)) 1:1 metal complexes of O2.Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.Tuning steric and electronic effects in transition-metal β-diketiminate complexesCopper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Cu-ZSM-5: A biomimetic inorganic model for methane oxidationX-ray absorption near-edge spectroscopy in bioinorganic chemistry: Application to M-O2 systems[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding.Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenasesMononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivityMacrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc ComplexesStepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.Copper is a Cofactor of the Formylglycine-Generating EnzymeGroup 5 chemistry supported by β-diketiminate ligands.Binuclear β-diketiminate complexes of copper(i).High-valent copper in biomimetic and biological oxidations.Side-on cupric-superoxo triplet complexes as competent agents for H-abstraction relevant to the active site of PHM.Cu(I)/O2 chemistry using a β-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity.An anionic, tetragonal copper(II) superoxide complex.Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation.Acid/base triggered interconversion of μ-η2:η2-peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands.Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C-H Bonds.Reactivity of a stable copper-dioxygen complex.Theoretical exploration of the oxidative properties of a [(tren Me1)CuO2]+ adduct relevant to copper monooxygenase enzymes: insights into competitive dehydrogenation versus hydroxylation reaction pathways.Copper-promoted methylene C-H oxidation to a ketone derivative by O2.Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions.beta-Diiminato ligand (L) transformations in reactions of KL with PI3 and I2 [L = {N(C6H3Pr(i)2-2,6)C(H)}2CPh].Can an ancillary ligand lead to a thermodynamically stable end-on 1 : 1 Cu–O2adduct supported by a β-diketiminate ligand?Electronic tuning of β-diketiminate ligands with fluorinated substituents: effects on the O2-reactivity of mononuclear Cu(i) complexesMixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores
P2860
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P2860
beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes.
description
2002 nî lūn-bûn
@nan
2002年の論文
@ja
2002年学术文章
@wuu
2002年学术文章
@zh
2002年学术文章
@zh-cn
2002年学术文章
@zh-hans
2002年学术文章
@zh-my
2002年学术文章
@zh-sg
2002年學術文章
@yue
2002年學術文章
@zh-hant
name
beta-diketiminate ligand backbone structural effects on Cu
@nl
beta-diketiminate ligand backb ...... oxo and bis(mu-oxo) complexes.
@en
type
label
beta-diketiminate ligand backbone structural effects on Cu
@nl
beta-diketiminate ligand backb ...... oxo and bis(mu-oxo) complexes.
@en
prefLabel
beta-diketiminate ligand backbone structural effects on Cu
@nl
beta-diketiminate ligand backb ...... oxo and bis(mu-oxo) complexes.
@en
P2093
P356
P1476
beta-diketiminate ligand backb ...... oxo and bis(mu-oxo) complexes.
@en
P2093
Anne M Reynolds
Douglas J E Spencer
Nermeen W Aboelella
Patrick L Holland
William B Tolman
P304
P356
10.1021/JA017820B
P407
P577
2002-03-01T00:00:00Z