Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
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Synthesis and reactions of N-heterocyclic carbene boranes.Carbene-Stabilized Main Group Radicals and Radical IonsBorylenes: An Emerging Class of Compounds.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.A Brief Survey of our Contribution to Stable Carbene Chemistry.Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anionAnchoring of silyl donors on a N-heterocyclic carbene through the cobalt-mediated silylation of benzylic C-H bonds.Activation of gaseous PH3 with low coordinate diaryltetrylene compounds.A theoretical study on the ring expansion of NHCs by silanes.Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters.N-heterocyclic carbene organocatalysts for dehydrogenative coupling of silanes and hydroxyl compounds.Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization.Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals.Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].N,P-Heterocyclic Germylene/B(C6 F5 )3 Adducts: A Lewis Pair with Multi-reactive Sites.Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2.Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.Diborabutatriene: an electron-deficient cumulene.Carbene-9-BBN ring expansions as a route to intramolecular frustrated Lewis pairs for CO2 reduction.Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs.Ring expansion of a ring expanded carbene.Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C-H and C-F Bond Activation.Unusual Fragmentation and Transformation of an N-Heterocyclic Carbene by a Stable Phosphonium-Borane peri-Functionalized Naphthalene.Reaction of Dihalodiboranes(4) with a N-Heterocyclic Silylene: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes.P-N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform.Reactivity of NHC Alane Adducts towards N-Heterocyclic Carbenes and Cyclic (Alkyl)(amino)carbenes: Ring Expansion, Ring Opening, and Al-H Bond Activation.Oxidative Cleavage of C=S and P=S Bonds at an Al(I) Center: Preparation of Terminally Bound Aluminum Sulfides.Facile insertion of a cyclic alkyl(amino) carbene carbon into the B-B bond of diboron(4) reagents.Synthesis of the First Example of the 12-Vertex-closo/12-Vertex-nido Biscarborane Cluster by a Metal-Free B-H Activation at a Phosphorus(III) Center.Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2.Cationic 5-phosphonio-substituted N-heterocyclic carbenes.C-N bond cleavage and ring expansion of N-heterocyclic carbenes using hydrosilanes.A Comparison of the Stability and Reactivity of Diamido- and Diaminocarbene Copper Alkoxide and Hydride Complexes.PNPCB heterocycles via thermal and Lewis acid catalyzed trans-hydroborations.The ambivalent chemistry of a free anionic N-heterocyclic carbene decorated with a malonate backbone: the plus of a negative charge.Effects of the electronic structure of five-membered N-heterocyclic carbenes on insertion of silanes and boranes into the NHC C–N bondActivation of the C–N bond of N-heterocyclic carbenes by inorganic elements
P2860
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P2860
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@en
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@nl
type
label
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@en
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@nl
prefLabel
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@en
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@nl
P2860
P50
P356
P1476
Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.
@en
P2093
Bruno Donnadieu
P2860
P304
P356
10.1002/ANIE.201005698
P407
P577
2010-12-01T00:00:00Z