Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane.
about
Profound methyl effects in drug discovery and a call for new C-H methylation reactions.Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.Catalytic insertion of aldehydes into dihalonitroacetophenones via sequential bond scission-aldol reaction-acyl transfer.Introduction of fluorine and fluorine-containing functional groups.Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes.Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides and iodides.Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.Ruthenium-Catalyzed meta-Selective C-H Mono- and Difluoromethylation of Arenes through ortho-Metalation Strategy.Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2 CH3 ).Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides.Visible-light induced di- and trifluoromethylation of N-benzamides with fluorinated sulfones for the synthesis of CF2H/CF3-containing isoquinolinediones.Copper/B2pin2-catalyzed C-H difluoroacetylation-cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles.Monofluoromethyl-Substituted Sulfonium Ylides: Electrophilic Monofluoromethylating Reagents with Broad Substrate Scopes.A Major Advance in the Synthesis of Fluoroalkyl Pyrazoles: Tuneable Regioselectivity and Broad Substitution Patterns.Chlorodifluoromethane-triggered formation of difluoromethylated arenes catalysed by palladium.Difluoroacetic Acid as a New Reagent for Direct C-H Difluoromethylation of Heteroaromatic Compounds.Visible-light-mediated direct difluoromethylation of alkynoates: synthesis of 3-difluoromethylated coumarins.Visible-light photoredox intramolecular difluoroacetamidation: facile synthesis of 3,3-difluoro-2-oxindoles from bromodifluoroacetamides.Supported gold nanoparticles catalyzed cis-selective semihydrogenation of alkynes using ammonium formate as the reductant.A Versatile Organocatalytic Approach for the Synthesis of Enantioenriched gem-Difluorinated Compounds.Synthesis of difluoromethyl thioethers from difluoromethyl trimethylsilane and organothiocyanates generated in situ.Visible-light-mediated radical oxydifluoromethylation of olefinic amides for the synthesis of CF2H-containing heterocycles.Visible-Light-Induced Hydrodifluoromethylation of Alkenes with a Bromodifluoromethylphosphonium Bromide.Visible-Light Photoredox-Catalyzed C-H Difluoroalkylation of Hydrazones through an Aminyl Radical/Polar Mechanism.Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes.Diastereoselective [3 + 2] cycloaddition of 3-ylideneoxindoles with in situ generated CF2HCHN2: syntheses of CF2H-containing spirooxindoles.Selective difluoroalkylation of alkenes by using visible light photoredox catalysis.Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.An efficient regioselective hydrodifluoromethylation of unactivated alkenes with TMSCF₂CO₂Et at ambient temperature.Highly effective copper-mediated gem-difluoromethylenation of arylboronic acids.Silver-catalyzed oxidative activation of benzylic C-H bonds for the synthesis of difluoromethylated arenes.Palladium-Catalyzed Remote Aryldifluoroalkylation of Alkenyl Aldehydes.Gold-Catalyzed Highly Selective Photoredox C(sp(2) )-H Difluoroalkylation and Perfluoroalkylation of Hydrazones.Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel.A General Synthesis of Fluoroalkylated Alkenes by Palladium-Catalyzed Heck-Type Reaction of Fluoroalkyl BromidesCopper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes
P2860
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P2860
Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh-hant
name
Copper-mediated difluoromethyl ...... butyl(difluoromethyl)stannane.
@en
Copper-mediated difluoromethylation of
@nl
type
label
Copper-mediated difluoromethyl ...... butyl(difluoromethyl)stannane.
@en
Copper-mediated difluoromethylation of
@nl
prefLabel
Copper-mediated difluoromethyl ...... butyl(difluoromethyl)stannane.
@en
Copper-mediated difluoromethylation of
@nl
P2093
P2860
P356
P1476
Copper-mediated difluoromethyl ...... butyl(difluoromethyl)stannane.
@en
P2093
Aditya Kulkarni
G K Surya Prakash
George A Olah
John-Paul Jones
Joseph K Swabeck
Kamil Masood
Somesh K Ganesh
P2860
P304
12090-12094
P356
10.1002/ANIE.201205850
P407
P577
2012-10-25T00:00:00Z