Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

Item
http://www.wikidata.org/entity/Q44450802
Taming of fluoroform: direct nucleophilic trifluoromethylation of Si, B, S, and C centers.Long-lived trifluoromethanide anion: a key intermediate in nucleophilic trifluoromethylations.Alpha-fluoro-alpha-nitro(phenylsulfonyl)methane as a fluoromethyl pronucleophile: efficient stereoselective Michael addition to chalcones.Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphineSynthesis of fluorinated chiral amines using N-tert-butylsulfinyl imines.Introduction of fluorine and fluorine-containing functional groups.Efficient 1,4-addition of alpha-substituted fluoro(phenylsulfonyl)methane derivatives to alpha,beta-unsaturated compounds.Nucleophilic difluoromethylation and difluoromethylenation of aldehydes and ketones using diethyl difluoromethylphosphonate.Copper-mediated difluoromethylation of aryl and vinyl iodides.Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane.Fluoride-catalyzed nucleophilic addition of PhSCF2SiMe3 to anhydrides: synthesis of γ-difluoromethylated γ-lactams.Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.Chlorodifluoromethane-triggered formation of difluoromethylated arenes catalysed by palladium.TrifluoromethyltrimethylsilaneCatalytic Asymmetric Construction of Stereogenic Carbon Centers that Feature agem-Difluoroalkyl GroupAddition of Electrophilic Radicals to 2-Benzyloxyglycals: Synthesis and Functionalization of Fluorinated α-C-Glycosides and Derivatives
P2860

Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

Item
http://www.wikidata.org/entity/Q44450802
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh-hant
name
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@en
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@nl
type
label
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@en
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@nl
prefLabel
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@en
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@nl
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P921
P356
P1433
P1476
Preparation of tri- and difluo ...... des, sulfoxides, and sulfones.
@en
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P921