CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
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Functionally diverse nucleophilic trapping of iminium intermediates generated utilizing visible lightEnantioselective additions of copper acetylides to cyclic iminium and oxocarbenium ionsAerobic Iron-Based Cross-Dehydrogenative Coupling Enables Efficient Diversity-Oriented Synthesis of Coumestrol-Based Selective Estrogen Receptor ModulatorsNi(II)-catalyzed dehydrative alkynylation of unactivated (hetero)aryl C-H bonds using oxygen: a user-friendly approach.Visible light-induced oxidative coupling reaction: easy access to Mannich-type products.Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions.Cu-catalyzed cross-dehydrogenative coupling: a versatile strategy for C-C bond formations via the oxidative activation of sp(3) C-H bonds.Visible light mediated sp(3) C-H bond functionalization of N-aryl-1,2,3,4-tetrahydroisoquinolines via Ugi-type three-component reaction.Multimetallic catalysed radical oxidative C(sp(3))-H/C(sp)-H cross-coupling between unactivated alkanes and terminal alkynes.Site-specific C-functionalization of free-(NH) peptides and glycine derivatives via direct C-H bond functionalization.Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process.Palladium-catalyzed C(sp(3))-H Arylation of N-Boc benzylalkylamines via a deprotonative cross-coupling process.Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process.Recent developments in the synthesis of five- and six-membered heterocycles using molecular iodine.The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations.Brønsted acid cocatalysts in photocatalytic radical addition of α-amino C-H bonds across Michael acceptors.Direct functionalization of (un)protected tetrahydroisoquinoline and isochroman under iron and copper catalysis: two metals, two mechanisms.Oxidative dehydrogenative couplings of pyrazol-5-amines selectively forming azopyrroles.Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of α-diazo carbonyls via radical dediazotization.α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp(3))-H Coupling.Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach.Tandem C(sp3)-H Arylation/Oxidation and Arylation/Allylic Substitution of Isoindolinones.Copper-catalyzed oxidative C(sp3)-H/C(sp2)-H cross-coupling en route to carbocyclic rings.Efficient domino approaches to multifunctionalized fused pyrroles and dibenzo[b,e][1,4]diazepin-1-ones.Effect of the ortho-hydroxy group of salicylaldehyde in the A3 coupling reaction: A metal-catalyst-free synthesis of propargylamine.Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysisAerobic and electrochemical oxidative cross-dehydrogenative-coupling (CDC) reaction in an imidazolium-based ionic liquid.Heterogeneous-gold-catalyzed acceptorless cross-dehydrogenative coupling of hydrosilanes and isocyanic acid generated in situ from urea.A cascade coupling strategy for one-pot total synthesis of β-carboline and isoquinoline-containing natural products and derivatives.Photochemically induced radical alkynylation of C(sp3)-H bonds.General one-pot reductive gem-bis-alkylation of tertiary lactams/amides: rapid construction of 1-azaspirocycles and formal total synthesis of (±)-cephalotaxine.Direct 2-acetoxylation of quinoline N-oxides via copper catalyzed C-H bond activation.Cobalt-catalyzed oxidative [3 + 2] cycloaddition reactions: an efficient synthesis of pyrrolo- and imidazo-[2,1-a]isoquinolines.Significant enhancement in the efficiency and selectivity of iron-catalyzed oxidative cross-coupling of phenols by fluoroalcohols.Copper-catalyzed Mannich-type oxidative β-functionalization of tertiary amines.Oxidative Alkane C-H Alkoxycarbonylation.N-Aryl Groups Are Ubiquitous in Cross-Dehydrogenative Couplings Because They Stabilize Reactive Intermediates.Visible-Light-Mediated Two-Fold Unsymmetrical C(sp3 )-H Functionalization and Double C-F Substitution.Direct α-C-H bond functionalization of unprotected cyclic amines.
P2860
Q24613419-17651120-3967-46CD-9B6A-5D8A3AC853DEQ26766080-0208FDE9-3871-4209-8230-4586BFCF2305Q29036826-5354E32C-E076-4F91-AD0A-F7B31FC51137Q33465404-295CA8B8-A8A9-449D-B11C-F5DF00C3355DQ34247767-C53015F6-C8F2-49E5-8A1E-C70BEB696A8DQ34479275-2FCEEA49-B257-4C6E-B521-17BBC32DF2B3Q34694674-0460DD70-CFBC-4982-B78F-D8DEA49643B8Q35574007-CD13F10A-C077-467D-B5D0-40A0F76B7486Q37060533-6C923460-4057-4727-9827-F6280C556022Q37112461-ECB2AB27-1890-4963-ACAD-D580001376D7Q37173876-3E935C8E-E775-4906-A533-9A62A35BB0F6Q37186144-349F4125-E834-4828-93A7-330D8601A8A1Q37365419-7D35BCDB-9CE7-4D04-99CA-05C0EFA06F57Q37986373-BC5CC7F2-A4E7-4485-B8D1-339793C930CDQ38001388-BF64C0CE-7E65-4425-85ED-C1CC5F407B38Q38161496-2ED662C0-0BBD-4637-BA56-4E371907789AQ39443796-39140C64-FBB8-410B-AD94-5A9091D5A3E0Q39449206-1E06A28E-FD2E-4C51-83B8-289C3079B4F8Q39495129-1AB2800C-E3E6-4D49-B368-E9550DFB1442Q39820733-09C6D644-AC80-4466-A531-356007DB6C57Q39914728-3ED78ACE-425D-4F30-8174-9B71FDCC930FQ39939511-CBBF49B7-1273-45F1-B176-B9E118EB12CCQ41056546-94C2333F-4C2B-4A16-BF1D-A93B669F31D7Q41664527-451D9828-1206-4F9B-B0AF-EF35A830B3C7Q42145721-C84BBCA0-9E16-4549-89B0-D0504F4A5CF6Q42293322-01758FC7-7849-4172-B118-C3DB72D55F02Q42764343-A4A6FAB7-9CC8-4891-9ED9-6CFB08B8BD71Q43038492-11444382-E986-4813-929A-6E267A22804BQ43447958-717E0628-396C-4292-AAB9-0C26BD2CE248Q43487301-F9D0EF77-EA67-4340-B446-39DF65B2CD68Q43512892-7F178D62-C892-4EAA-9338-87A1632B171CQ44154093-96897B50-E975-4A5D-9550-A64E58CF4E2DQ45853444-EA65F681-0D90-4F23-89EF-D90717F81C4DQ46092505-93DFA3A3-3DAB-40FC-8027-A668FBFCF847Q47570804-56FDA715-A492-4168-B6FC-1A9025A3BCE6Q47899582-F87D17F3-5988-45D4-8312-C192C3324AC7Q48042075-A7BBEA0B-E23A-4BEA-B5A0-CDA3A977D36EQ48061241-5DC34E44-10E0-4421-812D-0423F53583B5Q48124729-57B04EA5-EBD8-4CFA-93B0-F91A16F1A7CEQ48186924-A14F8B48-99C5-4792-8835-7A1198E4CDAF
P2860
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@en
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@nl
type
label
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@en
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@nl
prefLabel
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@en
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@nl
P356
P1476
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
@en
P2093
Chao-Jun Li
Zhiping Li
P304
11810-11811
P356
10.1021/JA0460763
P407
P577
2004-09-01T00:00:00Z