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Expanding the scope of C-H amination through catalyst design.

Expanding the scope of C-H amination through catalyst design.

http://www.wikidata.org/entity/Q45162229

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Direct stereospecific synthesis of unprotected N-H and N-Me aziridines from olefins Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion Intermolecular Ritter-type C-H amination of unactivated sp3 carbons.Synthesis of 1,3-diamines through rhodium-catalyzed C-H insertion Selective intermolecular amination of C-H bonds at tertiary carbon centers.Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bonds.Examination of the mechanism of Rh(2)(II)-catalyzed carbazole formation using intramolecular competition experiments.Iodobenzene catalysed synthesis of spirofurans and benzopyrans by oxidative cyclisation of vinylogous esters.Development of a concise synthesis of (-)-oseltamivir (Tamiflu)Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azides Synthesis and reactivity of unique heterocyclic structures en route to substituted diamines.Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.Synthesis of (carbo)nucleoside analogues by [3+2] annulation of aminocyclopropanes.Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.An expedient synthesis of maraviroc (UK-427,857) via C-H functionalization.Highly functionalized donor-acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids Rh(II)2-catalyzed synthesis of α-, β-, or δ-carbolines from aryl azides.Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangement Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.Scope and mechanistic study of the ruthenium-catalyzed ortho-C-H bond activation and cyclization reactions of arylamines with terminal alkynes.Syntheses of manzacidins: a stage for the demonstration of synthetic methodologies.Formation of six- vs. five-membered cyclic sulfones by C-H insertion.Catalytic C-H amination for the preparation of substituted 1,2-diamines.Dirhodium-catalyzed C-H arene amination using hydroxylamines.Rh(2)(II)-catalyzed synthesis of carbazoles from biaryl azides.Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation.A stereoselective synthesis of the bromopyrrole natural product (-)-agelastatin A.Functionalizing the γ-Position of α-Diazo-β-ketoesters.P450-catalyzed intramolecular sp(3) C-H amination with arylsulfonyl azide substrates.Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles.Diastereotopos-differentiating C-H activation reactions at methylene groups.Transition-metal-catalyzed aminations and aziridinations of C-H and C=C bonds with iminoiodinanes.Trends in applying C-H oxidation to the total synthesis of natural products.Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions.Modern advances in heterocyclic chemistry in drug discovery.Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand.A general method for artificial metalloenzyme formation through strain-promoted azide-alkyne cycloaddition.Metal-Catalysed Azidation of Organic Molecules

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P2860

Expanding the scope of C-H amination through catalyst design.

http://www.wikidata.org/entity/Q45162229

description

2004 nî lūn-bûn

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2004年の論文

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2004年学术文章

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2004年学术文章

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2004年学术文章

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2004年学术文章

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2004年学术文章

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2004年学术文章

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2004年學術文章

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2004年學術文章

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name

Expanding the scope of C-H amination through catalyst design.

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Expanding the scope of C-H amination through catalyst design.

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Expanding the scope of C-H amination through catalyst design.

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Expanding the scope of C-H amination through catalyst design.

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prefLabel

Expanding the scope of C-H amination through catalyst design.

@en

Expanding the scope of C-H amination through catalyst design.

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Journal of the American Chemical Society

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Expanding the scope of C-H amination through catalyst design.

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P2093

Christine G Espino

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J Du Bois

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Kristin Williams Fiori

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Mihyong Kim

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15378-15379

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scholarly article

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10.1021/JA0446294

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47

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126

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2004-12-01T00:00:00Z

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15563154

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