Dichlorosilylene: a high temperature transient species to an indispensable building block.
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[2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles.Reaction of silylene with sulfur dioxide: some gas-phase kinetic and theoretical studies.Donor-acceptor chemistry in the main group.Advances in Phosphasilene Chemistry.Alcohol-Induced C-N Bond Cleavage of Cyclometalated N-Heterocyclic Carbene Ligands with a Methylene-Linked Pendant Imidazolium Ring.[4-tBu-2,6-{P(O)(OiPr)2}2C6H2SnL]+: an NHC-stabilized organotin(II) cation and related derivatives.Thermal Synthesis of Perchlorinated Oligosilanes: A Fresh Look at an Old Reaction.Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes.Unraveling the Amine-Induced Disproportionation Reaction of Perchlorinated Silanes-A DFT Study.Dimerization of a marginally stable disilenyl germylene to tricyclic systems: evidence for reversible NHC-coordination.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene.Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions.A multiply functionalized base-coordinated Ge(II) compound and its reversible dimerization to the digermene.Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.A Disilene Base Adduct with a Dative Si-Si Single Bond.Trapping a Silicon(I) Radical with Carbenes: A Cationic cAAC-Silicon(I) Radical and an NHC-Parent-Silyliumylidene Cation.Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal.Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs.Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand.Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).A comparative study of the structure and bonding in heavier pnictinidene complexes [(ArE)M(CO)n] (E = As, Sb and Bi; M = Cr, Mo, W and Fe).Unusual Fragmentation and Transformation of an N-Heterocyclic Carbene by a Stable Phosphonium-Borane peri-Functionalized Naphthalene.Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.1,3,2-Diazaborole-derived carbene complexes of boron.Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.Synthesis, Characterization, and Theoretical Investigation of Two-Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-Accepting Carbenes.Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.Facile routes to abnormal-NHC-cobalt(ii) complexes.Phosphinosilylenes as a novel ligand system for heterobimetallic complexes.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.Mixed valence η6-arene cobalt(I) and cobalt(II) compound.Reactivity of an NHC-stabilized silylene towards ketones. Formation of silicon bis-enolates vs. bis-silylation of the C[double bond, length as m-dash]O bond.Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights† †Dedicated to the memory of Paul von R. Schleyer. ‡ ‡Electronic supplementary information (ESI) available: CIF files giOn the Reactivity of the Silylene PhC(NtBu)2SiNPh2toward Organic SubstratesMetal free and selective activation of one C–F bond in a bound CF3 group
P2860
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P2860
Dichlorosilylene: a high temperature transient species to an indispensable building block.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
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2012年學術文章
@zh-hant
name
Dichlorosilylene: a high tempe ...... indispensable building block.
@en
Dichlorosilylene: a high tempe ...... indispensable building block.
@nl
type
label
Dichlorosilylene: a high tempe ...... indispensable building block.
@en
Dichlorosilylene: a high tempe ...... indispensable building block.
@nl
prefLabel
Dichlorosilylene: a high tempe ...... indispensable building block.
@en
Dichlorosilylene: a high tempe ...... indispensable building block.
@nl
P356
P1476
Dichlorosilylene: a high tempe ...... indispensable building block.
@en
P2093
Rajendra S Ghadwal
Ramachandran Azhakar
P304
P356
10.1021/AR300196U
P577
2012-11-27T00:00:00Z