about
Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefinationC-H bonds as ubiquitous functionality: a general approach to complex arylated imidazoles via regioselective sequential arylation of all three C-H bonds and regioselective N-alkylation enabled by SEM-group transposition.Auxiliary-assisted palladium-catalyzed arylation and alkylation of sp2 and sp3 carbon-hydrogen bonds.The total synthesis of K-252c (staurosporinone) via a sequential C-H functionalisation strategy.Arenium ions are not obligatory intermediates in electrophilic aromatic substitution.Biomimetic Aerobic C-H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes.Facile C-H bond cleavage via a proton-coupled electron transfer involving a C-H...Cu(II) interaction.Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis.Ligand-Enabled Meta-C-H Alkylation and Arylation Using a Modified Norbornene.Mobilizing Cu(I) for carbon-carbon bond forming catalysis in the presence of thiolate. Chemical mimicking of metallothioneins.Regioselective C-H bond amination by aminoiodanes.Copper-catalyzed C-2 arylation or vinylation of indole derivatives with iodonium salts.Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.Regiospecific syntheses of functionalized diaryliodonium tosylates via [hydroxy(tosyloxy)iodo]arenes generated in situ from (diacetoxyiodo)arenes.Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium SaltsActivation of remote meta-C-H bonds assisted by an end-on templatePalladium-catalyzed direct arylation and cyclization of o-iodobiaryls to a library of tetraphenylenes.Manganese-Mediated Coupling Reaction of Vinylarenes and Aliphatic Alcohols.A Domino Oxidation/Arylation/Protodecarboxylation Reaction of Salicylaldehydes: Expanded Access to meta-Arylphenols.Pd(II)-catalyzed ortho- or meta-C-H olefination of phenol derivativesTBDPS and Br-TBDPS protecting groups as efficient aryl group donors in Pd-catalyzed arylation of phenols and anilines.Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines.On the Mechanism of Pd(0)-Catalyzed, Cu(I) Carboxylate-Mediated Thioorganic-Boronic Acid Desulfitative Coupling. A Non-innocent Role for Carboxylate Ligand.Cross-coupling of remote meta-C-H bonds directed by a U-shaped template.The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of DioxasilinesAn aromatic Glaser-Hay reactionDirect arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I).Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions.If C-H bonds could talk: selective C-H bond oxidationCommemorating two centuries of iodine research: an interdisciplinary overview of current research.High-valent organometallic copper and palladium in catalysis.Catalytic selective synthesis.Organometallic aspects of transition-metal catalysed regioselective C-H bond functionalisation of arenes and heteroarenes.Arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy.Transition metal catalyzed meta-C-H functionalization of aromatic compounds.Directed aromatic functionalization.Selective mono-alkylation of N-methoxybenzamides.Palladium catalysed meta-C-H functionalization reactions.Reaching the south: metal-catalyzed transformation of the aromatic para-position.
P2860
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P2860
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh
2009年學術文章
@zh-hant
name
A meta-selective copper-catalyzed C-H bond arylation.
@en
A meta-selective copper-catalyzed C-H bond arylation.
@nl
type
label
A meta-selective copper-catalyzed C-H bond arylation.
@en
A meta-selective copper-catalyzed C-H bond arylation.
@nl
prefLabel
A meta-selective copper-catalyzed C-H bond arylation.
@en
A meta-selective copper-catalyzed C-H bond arylation.
@nl
P2860
P356
P1433
P1476
A meta-selective copper-catalyzed C-H bond arylation.
@en
P2093
Matthew J Gaunt
Robert J Phipps
P2860
P304
P356
10.1126/SCIENCE.1169975
P407
P577
2009-03-01T00:00:00Z