Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
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Building Bridges: Biocatalytic C–C-Bond Formation toward Multifunctional ProductsComparative analysis of tertiary alcohol esterase activity in bacterial strains isolated from enrichment cultures and from screening strain libraries.Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric SynthesisEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsNickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.Advances in the synthesis of glycosidic macrolides: clavosolides A-D and cyanolide A.Synthetic applications and inversion dynamics of configurationally stable 2-lithio-2-arylpyrrolidines and -piperidines.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.Biocatalytic synthesis of optically active tertiary alcohols.Electrophilic amination: the case of nitrenoids.Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (-)-Clavosolide A.Synthesis and Utility of Dihydropyridine Boronic Esters.Enantioselective syntheses of indanes: from organocatalysis to C-H functionalization.Stereospecific functionalizations and transformations of secondary and tertiary boronic esters.Enantiospecific Alkynylation of Alkylboronic Esters.Tertiary alcohol preferred: Hydroxylation of trans-3-methyl-L-proline with proline hydroxylases.Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.Stereocontrolled Total Synthesis of (-)-Stemaphylline.Substrate-Determined Diastereoselectivity in an Enzymatic Carboligation.Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds.Enantioselective synthesis of (R)-tolterodine using lithiation/borylation-protodeboronation methodology.Alkynyl Moiety for Triggering 1,2-Metallate Shifts: Enantiospecific sp2 -sp3 Coupling of Boronic Esters with p-Arylacetylenes.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation.Retention or inversion in stereospecific nickel-catalyzed cross-coupling of benzylic carbamates with arylboronic esters: control of absolute stereochemistry with an achiral catalyst.Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium SpeciesOne-pot synthesis of four-coordinate boron(III) complexes by the ligand-promoted organic group migration between boronic acids.Selective uni- and bidirectional homologation of diborylmethane.Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Allylation of nitrosobenzene with pinacol allylboronates. A regioselective complement to peroxide oxidation.Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis.Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration.Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement.Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine-Pd Complex.Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes.Pseudomonas putida esterase contains a GGG(A)X-motif confering activity for the kinetic resolution of tertiary alcohols.Solvent and TMEDA effects on the configurational stability of chiral lithiated aryloxiranes.Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings.
P2860
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P2860
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@en
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@nl
type
label
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@en
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@nl
prefLabel
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@en
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.
@nl
P356
P1433
P1476
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols
@en
P2093
Jake L Stymiest
Rosalind M French
P2888
P304
P356
10.1038/NATURE07592
P407
P577
2008-12-01T00:00:00Z
P5875
P6179
1024872191