about
Novel 10-I-3 hypervalent iodine-based compounds for electrophilic trifluoromethylation.Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent.Development of the titanium-TADDOLate-catalyzed asymmetric fluorination of β-ketoesters.Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3H-1λ(3),2-benziodaoxol-3-one.Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent.Enantioselective 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines to unsaturated nitriles catalyzed by NiII-Pigiphos.Addition of the ortho-C-H bonds of phenol across an olefin catalysed by a chiral iridium(I) diphosphine complex.Chiral iridium [corrected] xyliphos complexes for the catalytic imine hydrogenation leading to the metolachlor herbicide: isolation of catalyst-substrate adducts.Iridium-imine and -amine complexes relevant to the (S)-metolachlor process: structures, exchange kinetics, and C-H activation by Iri causing racemization.Nickel(II)-catalyzed highly enantioselective hydrophosphination of methacrylonitrile.Zinc-mediated formation of trifluoromethyl ethers from alcohols and hypervalent iodine trifluoromethylation reagents.Importance of Nonclassical σ-Hole Interactions for the Reactivity of λ3-Iodane Complexes.P-Trifluoromethyl ligands derived from Josiphos in the Ir-catalysed hydrogenation of 3,4-dihydroisoquinoline hydrochlorides.Ti(IV)-catalyzed asymmetric sulfenylation of 1,3-dicarbonyl compounds.S-Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational Study.Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles.Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes.Irreversible Cysteine-Selective Protein Labeling Employing Modular Electrophilic Tetrafluoroethylation Reagents.Electrophilic trifluoromethylation of S-hydrogen phosphorothioates."Why and How it Works": The Development of Hypervalent Iodine Reagents as an Illustration for the Collaboration of Chemical Synthesis with Modeling and Simulation.Exposing the Origins of Irreproducibility in Fluorine NMR SpectroscopyFluor-NMR-Spektroskopie rekalibriertConfusing Quantitative Descriptions ofBrønstedLowryAcidBase Equilibria in Chemistry Textbooks - A Critical Review and Clarifications for Chemical EducatorsQ56337341Radical Trifluoromethoxylation of Arenes Triggered by a Visible-Light-Mediated N-O Bond Redox FragmentationPhosphane lone-pair energies as a measure of ligand donor strengths and relation to activation energiesToward an Alkene Hydroamination Catalyst: Static and Dynamic ab Initio DFT StudiesNMR-Solution Structures and Affinities for the Human Somatostatin G-Protein-Coupled Receptors hsst1â 5 of CF3 Derivatives of Sandostatin® (Octreotide)Recent Advances in Electrophilic CF 3 -Transfer Using Hypervalent Iodine(III) ReagentsOne-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic TrifluoromethylationPyridyl Radical Cation for C−H Amination of ArenesPyridyl Radical Cation for C−H Amination of ArenesNi(II) complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefinsTitanium-catalyzed stereoselective geminal heterodihalogenation of beta-ketoestersLigand Electronic Effect in Enantioselective Palladium-Catalyzed Copolymerization of Carbon Monoxide and Propene This work was supported by the ETH Zürich. We thank Novartis AG and Solvias AG, Basel, for the donation of chemicalsThe mechanism of catalytic enantioselective fluorination: computational and experimental studiesMild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)-CF(3) reagentsTitanium(IV)-catalyzed enantioselective sulfenylation of beta-ketoestersPalladium-catalyzed enantioselective allylic phosphinationNi(II)-catalyzed enantioselective Nazarov cyclizations
P50
Q33231221-919F31E7-2890-422E-9361-7AFE32D431EFQ34588669-4C6A80BC-EB12-4C6C-A919-38F78550D311Q38818941-A16B9628-E024-4759-8907-0922CEAEB7F0Q41880050-CD63AE9C-7E85-4A8F-A941-D8688C716BC5Q43266010-D8D11664-6A94-43F8-8FB4-AD975D92448BQ43422550-E80344A0-9D18-4235-836F-9AED0449C6DFQ44409112-43A18C88-BD6B-43D6-8880-70ED5D7DD9DAQ44706224-CD357499-68A8-4AE4-8857-4F56108F26C4Q45066321-62F905E2-D085-4CE3-8D42-87481D1921B2Q45145386-EC055EF1-4E9F-4DBB-B11C-E0A832E5398FQ46015476-43CECDCF-A097-43E1-9F13-5A0E8D8A6F45Q46291771-F9F9A094-3D3E-476A-ADF9-E8900C4BA860Q46702654-352E2E6E-5AAB-46DE-9827-9B5F3F54E93FQ46988069-0A4C994A-F8CA-4FD1-8DBB-79A6647C4603Q48044625-DE1C2DF4-5E70-4E21-9294-C117BAA0807AQ48150667-D4927F0A-0692-4364-8A76-2963B3648196Q48216925-04E23E04-D2F2-46BD-ADE7-576CF42851DAQ48240125-AEA6FCB8-6799-4161-9E37-8F821A432854Q51581941-FF7CEBAE-DAD2-4E51-9704-62A5D1B3EBDBQ51583320-F094220A-DF31-465B-BEC0-4D1E6F9F9F38Q55952108-1AFCEF42-F0F8-4003-8A81-41D31E052182Q55952109-9F7559BD-FCFC-4A72-9E27-1069E9D108BBQ56083721-B966049D-A39F-4D3F-BB74-0CBFE6C5D522Q56337341-5C928041-A48C-4574-B626-DC7722FF6689Q57461277-4D7579F0-B839-4BA7-A926-43A250393FB2Q57971625-5900052B-23FF-43D7-9C49-43F89471CDCFQ57971627-9FA0BAFB-5C5F-4614-B4EE-949873530B9CQ59201324-E181E4F7-D6B5-49B9-A4AE-C51C200C29FFQ59487479-74C53790-AEDD-43F7-B643-AFAF53153236Q59487480-1FC94826-6818-4960-9769-624852A1ABC4Q64168756-579C2F71-FCBC-4A0F-9D89-CDC5BF32CB93Q64168759-3A95AE8C-C4B8-4407-A9A4-030C1A677341Q73065102-01F6F438-42D8-498C-8E0B-C28ACD02A88DQ73365683-ADF8B0EF-A01B-45E9-9BD4-62E32AF27168Q74166230-8F684949-EF22-4128-B897-7BD0DD982749Q78687504-91E7AD01-6631-435A-A086-D7C677A0C189Q80919862-966B2EAA-14E5-4987-99B6-641651EFC293Q81109624-A3E4D69E-0052-4A50-9025-F825AC04CA14Q81321241-99185E5B-5890-4BE4-95A0-E2F5456CAC3CQ81998460-3B7547ED-B6E3-42D3-91AB-1FECD3FE7711
P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Antonio Togni
@ast
Antonio Togni
@en
Antonio Togni
@es
Antonio Togni
@nl
Antonio Togni
@sl
type
label
Antonio Togni
@ast
Antonio Togni
@en
Antonio Togni
@es
Antonio Togni
@nl
Antonio Togni
@sl
prefLabel
Antonio Togni
@ast
Antonio Togni
@en
Antonio Togni
@es
Antonio Togni
@nl
Antonio Togni
@sl
P1053
P-8428-2014
P106
P108
P1153
7005978359
P21
P31
P3829
P496
0000-0003-3868-1799