From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.
about
Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre.Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol.Formation of N-heterocyclic, donor-stabilized borenium ions.New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.A silyl radical formed by muonium addition to a silylene.E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.Synthesis of a donor-stabilized silacyclopropan-1-one.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water.Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.Reversible formation of a blue arsasilene and isolation of air-stable emissive disilenes.Lewis base stabilized oxophosphonium ions.A Stable Monomeric SiO2 Complex with Donor-Acceptor Ligands.Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor.An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine.From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-.Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.Germanium(iii) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activationsA Stable Silanone with a Three-Coordinate Silicon Atom: A Century-Long Wait is Over
P2860
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P2860
From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
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2007年学术文章
@zh
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
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2007年学术文章
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2007年學術文章
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2007年學術文章
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name
From a stable silylene to a mi ...... -oxygen double-bond character.
@en
From a stable silylene to a mi ...... -oxygen double-bond character.
@nl
type
label
From a stable silylene to a mi ...... -oxygen double-bond character.
@en
From a stable silylene to a mi ...... -oxygen double-bond character.
@nl
prefLabel
From a stable silylene to a mi ...... -oxygen double-bond character.
@en
From a stable silylene to a mi ...... -oxygen double-bond character.
@nl
P356
P1476
From a stable silylene to a mi ...... -oxygen double-bond character.
@en
P2093
Markus Brym
Shenglai Yao
P304
P356
10.1002/ANIE.200700398
P407
P577
2007-01-01T00:00:00Z