A new type of N-heterocyclic silylene with ambivalent reactivity.
about
Formation of N-heterocyclic, donor-stabilized borenium ions.New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.Group 14 inorganic hydrocarbon analogues.Cations and dications of heavier group 14 elements in low oxidation states.Advances in Phosphasilene Chemistry.Stable singlet carbenes as mimics for transition metal centers.From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.A silyl radical formed by muonium addition to a silylene.Activation of gaseous PH3 with low coordinate diaryltetrylene compounds.EH3 (E = N, P, As) and H2 activation with N-heterocyclic silylene and germylene homologues.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.Reduction of the dihalocyclopentasilanes. A quest for a homocyclic silylene.Oligomerization of N-Heterocyclic Silylene into Zwitterionic Silenes.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.Reversible formation of a blue arsasilene and isolation of air-stable emissive disilenes.New insights into small molecule activation by acyclic silylenes: a computational investigation.Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor.An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine.Synthesis and tunable reactivity of N-heterocyclic germylene.Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-.Aromatic ylide-stabilized carbocyclic silylene.Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes.Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl].Synthesis of γ-amidine-functionalized dianionic β-diketiminato lanthanide amides and trianionic β-diketiminato Na/Sm heterobimetallic complexes and their reactivity in polymerization of L-lactide.Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.A zwitterionic hydrocarbon-soluble borenium ion based on a β-diketiminate backbone.Metal free and selective activation of one C–F bond in a bound CF3 groupDouble N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene
P2860
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P2860
A new type of N-heterocyclic silylene with ambivalent reactivity.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
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2006年學術文章
@zh-hant
name
A new type of N-heterocyclic silylene with ambivalent reactivity.
@en
A new type of N-heterocyclic silylene with ambivalent reactivity.
@nl
type
label
A new type of N-heterocyclic silylene with ambivalent reactivity.
@en
A new type of N-heterocyclic silylene with ambivalent reactivity.
@nl
prefLabel
A new type of N-heterocyclic silylene with ambivalent reactivity.
@en
A new type of N-heterocyclic silylene with ambivalent reactivity.
@nl
P2093
P356
P1476
A new type of N-heterocyclic silylene with ambivalent reactivity.
@en
P2093
Dieter Lentz
Markus Brym
Shenglai Yao
P304
P356
10.1021/JA062928I
P407
P577
2006-08-01T00:00:00Z