Electron-Precise Coordination Modes of Boron-Centered Ligands
about
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.Diborane(4)-metal bonding: between hydrogen bridges and frustrated oxidative addition.New ligand platforms featuring boron-rich clusters as organomimetic substituents(.)Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation.Transition metal borylene complexes.Boron and nucleic acid chemistries: merging the best of both worlds.Recent developments in the coordination chemistry of multidentate ligands featuring a boron moiety.Reactive p-block cations stabilized by weakly coordinating anions.Triaminoborane-bridged diphosphine complexes with Ni and Pd: coordination chemistry, structures, and ligand-centered reactivity.Regioselective Photoisomerization/C-C Bond Formation of Asymmetric B(ppy)(Mes)(Ar): The Role of the Aryl Groups on Boron.Functional group migrations between boron and metal centres within transition metal-borane and -boryl complexes and cleavage of H-H, E-H and E-E' bonds.Borylenes: An Emerging Class of Compounds.Dehydrocoupling and Silazane Cleavage Routes to Organic-Inorganic Hybrid Polymers with NBN Units in the Main Chain.(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center.First-row transition-metal-diborane and -borylene complexes.Metal-ligand multiple bonds as frustrated Lewis pairs for C-H functionalization.Cationic tricoordinate boron intermediates: borenium chemistry from the organic perspective.Isolation, structure and reactivity of a scandium boryl oxycarbene complex.Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N3)].Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido-borylene-1:2κ(2) B:B-[1(η(5))-penta-methyl-cyclo-penta-dien-yl](tri-cyclo-hexyl-phosphane-2κP)iron(II)platinum(II) benzene monosolvate.A d(10) Ni-(H(2)) adduct as an intermediate in H-H oxidative addition across a Ni-B bond.Cadmium Compounds with an [N3C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species.Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)2CH] via metal-templated synthesis.Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes.Reductive borylene-CO coupling with a bulky arylborylene complex.Syntheses and characterization of new vinyl-borylene complexes by the hydroboration of alkynes with [(μ3-BH)(Cp*RuCO)2(μ-CO)Fe(CO)3].Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.Redox and anion exchange chemistry of a stibine-nickel complex: writing the L, X, Z ligand alphabet with a single element.Reversible intramolecular coupling of the terminal borylene and a carbonyl ligand of [Cp(CO)2Mn=B-tBu].Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.An electron-precise, tetrahedral μ3 boride complex.Single, double, triple bonds and chains: the formation of electron-precise B-B bonds.Synthesis and structure of the first heterodinuclear bis(borylene) complexes.Stabilization of diborane(4) by transition metal fragments and a novel metal to π Dewar-Chatt-Duncanson model of back donation.Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal→Borane Interaction.Transition metals as Lewis bases: "Z-type" boron ligands and metal-to-boron dative bonding.Forging Unsupported Metal-Boryl Bonds with Icosahedral Carboranes.Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides.A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification.B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.
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P2860
Electron-Precise Coordination Modes of Boron-Centered Ligands
description
im Juli 2010 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 01 July 2010
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в липні 2010
@uk
name
Electron-Precise Coordination Modes of Boron-Centered Ligands
@en
Electron-Precise Coordination Modes of Boron-Centered Ligands
@nl
type
label
Electron-Precise Coordination Modes of Boron-Centered Ligands
@en
Electron-Precise Coordination Modes of Boron-Centered Ligands
@nl
prefLabel
Electron-Precise Coordination Modes of Boron-Centered Ligands
@en
Electron-Precise Coordination Modes of Boron-Centered Ligands
@nl
P356
P1433
P1476
Electron-precise coordination modes of boron-centered ligands
@en
P2093
Achim Schneider
P304
P356
10.1021/CR900333N
P577
2010-07-01T00:00:00Z