Large rate accelerations in the stille reaction with tri-2-furylphosphine and triphenylarsine as palladium ligands: mechanistic and synthetic implications
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Synthesis of 19-substituted geldanamycins with altered conformations and their binding to heat shock protein Hsp90Optimising stereoselectivity in intramolecular Diels-Alder reactions of pentadienyl acrylates: synthetic and computational investigations into the "steric directing group" approach.Nano-palladium is a cellular catalyst for in vivo chemistryHighly functionalized organomagnesium reagents prepared through halogen-metal exchange.Elucidating the structure-property relationships of donor-π-acceptor dyes for dye-sensitized solar cells (DSSCs) through rapid library synthesis by a one-pot procedure.A practical method for the generation of organoarsenic nucleophiles towards the construction of a versatile arsenic library.Applications of and alternatives to pi-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions.Asymmetric synthesis of naturally occurring spiroketals.Palladium-catalyzed completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophilesTheoretical aspects of palladium-catalysed carbon-carbon cross-coupling reactions.Total synthesis of indole-derived allocolchicine analogues exhibiting strong apoptosis-inducing activity.An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2',3'-d]arsoleSynthesis of dibenzothiophenes and related classes of heterocycles by using functionalized dithiocarbamates.Resolution of the atropochiral biminap ligand and applications in asymmetric catalysis.Callipeltosides A, B and C: Total Syntheses and Structural Confirmation.Rate and mechanism of the oxidative addition of phenyl iodide to Pd0 ligated by triphenylarsine: evidence for the formation of a T-shaped complex.Nickel-catalyzed manipulation of tertiary phosphines via highly selective C-P bond cleavage.Synthesis of ring-oxidized retinoids as substrates of mouse class I alcohol dehydrogenase (ADH1).Thwarting beta-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction This research was supported by the National Institutes of Health (grant GM-12389). M.O. thanks the Deutsche ForschungsgemeinPractical continuous-flow trapping metalations of functionalized arenes and heteroarenes using TMPLi in the presence of Mg, Zn, Cu, or La halides.Decarboxylative cross-coupling of mesylates catalyzed by copper/palladium systems with customized imidazolyl phosphine ligands.Continuous flow magnesiation of functionalized heterocycles and acrylates with TMPMgCl⋅LiCl.Bis(diethylamino)(pentafluorophenyl)phosphane – a Push–Pull Phosphane Available for Coordination.Total syntheses of smenothiazoles A and B.Nickel catalyzed enantioselective hydroarsination of nitrostyrene.Two Enabling Strategies for the Stereoselective Conversion of Internal Alkynes into Trisubstituted Alkenes.Zn-, Mg-, and Li-TMP Bases for the Successive Regioselective Metalations of the 1,5-Naphthyridine Scaffold (TMP=2,2,6,6-Tetramethylpiperidyl).Practical and economic lithiations of functionalized arenes and heteroarenes using Cy2NLi in the presence of Mg, Zn or La halides in a continuous flow.Total synthesis of (-)-deguelin via an iterative pyran-ring formation strategy.Macrocyclic polyenynes: a stereoselective route to vinyl-ether-containing skipped diene systems.Concise total syntheses of amphidinolides C and F.Iridium(I)-catalyzed C-H Borylation of α,β-Unsaturated Esters with Bis(pinacolato)diboron.Stereoselective Pd(0) catalysed five component cascade synthesis of complex Z,Z-bisallylamines.Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.As-stereogenic C2-symmetric organoarsines: synthesis and enantioselective self-assembly into a dinuclear triple-stranded helicate with copper iodide.Arsole-Containing π-Conjugated Polymer by the Post-Element-Transformation Technique.Decarboxylative dearomatization and mono-α-arylation of ketones.Rigid tetrazine fluorophore conjugates with fluorogenic properties in the inverse electron demand Diels-Alder reaction.A theoretical DFT-based and experimental study of the transmetalation step in Au/Pd-mediated cross-coupling reactions.The Stille Reaction
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P2860
Large rate accelerations in the stille reaction with tri-2-furylphosphine and triphenylarsine as palladium ligands: mechanistic and synthetic implications
description
im Dezember 1991 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в грудні 1991
@uk
name
Large rate accelerations in th ...... tic and synthetic implications
@en
Large rate accelerations in th ...... tic and synthetic implications
@nl
type
label
Large rate accelerations in th ...... tic and synthetic implications
@en
Large rate accelerations in th ...... tic and synthetic implications
@nl
prefLabel
Large rate accelerations in th ...... tic and synthetic implications
@en
Large rate accelerations in th ...... tic and synthetic implications
@nl
P356
P1476
Large rate accelerations in th ...... tic and synthetic implications
@en
P2093
Bala Krishnan
Vittorio Farina
P304
P356
10.1021/JA00025A025
P407
P577
1991-12-01T00:00:00Z