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Can low-valent germanium chemistry be practiced under ambient conditions? A tale of a water-stable yet reactive germylene monochloride complex.Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene.Reaction of silylene with sulfur dioxide: some gas-phase kinetic and theoretical studies.New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.Group 14 inorganic hydrocarbon analogues.Cations and dications of heavier group 14 elements in low oxidation states.Reaction of a diaryldigermyne with ethyleneBasic Reactivity Pattern of a Cyclic Disilylated Germylene.Coordination chemistry of disilylated stannylenes with group 10 d10 transition metals: silastannene vs stannylene complexation.Performance of Møller-Plesset second-order perturbation theory and density functional theory in predicting the interaction between stannylenes and aromatic moleculesDispersion energy enforced dimerization of a cyclic disilylated plumbyleneCoordination chemistry of cyclic disilylated stannylenes and plumbylenes to group 4 metallocenes.Formation and properties of a bicyclic silylated digermene.A cyclic disilylated stannylene: synthesis, dimerization, and adduct formation.Cleavage of the Sn-Sn multiple bond in a distannyne by cyclooctatetraene: formation of the pi-bound inverse sandwich complex [(Ar'Sn)2(mu2-eta2:eta3-cot)].Cyclic Disilylated and Digermylated Germylenes.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.[4-tBu-2,6-{P(O)(OiPr)2}2C6H2SnL]+: an NHC-stabilized organotin(II) cation and related derivatives.Unusual coordination of tetrylenes to molybdenum carbonyl fragments.Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules.Accessing Low-Valent Inorganic Cations by Using an Extremely Bulky N-Heterocyclic Carbene.Alkyne Addition and Insertion Reactions of [(Me3 Si)3 Si]2 Ge⋅PMe3.Oligomerization of N-Heterocyclic Silylene into Zwitterionic Silenes.Dimerization of a marginally stable disilenyl germylene to tricyclic systems: evidence for reversible NHC-coordination.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds.The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes.Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.Stabilization of a diphosphagermylene through pπ-pπ interactions with a trigonal-planar phosphorus center.1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids.Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.Facile activation of alkynes with a boraguanidinato-stabilized germylene: a combined experimental and theoretical study.Oxoborane (RBO) Complexation and Concomitant Electrophilic Bond Activation Processes.Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion.
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P2860
description
im August 2009 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 01 August 2009
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в серпні 2009
@uk
name
Stable Heavier Carbene Analogues
@en
Stable Heavier Carbene Analogues
@nl
type
label
Stable Heavier Carbene Analogues
@en
Stable Heavier Carbene Analogues
@nl
prefLabel
Stable Heavier Carbene Analogues
@en
Stable Heavier Carbene Analogues
@nl
P356
P1433
P1476
Stable heavier carbene analogues
@en
P2093
Takahiro Sasamori
P304
P356
10.1021/CR900093S
P577
2009-08-01T00:00:00Z