Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent

Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent

Item
http://www.wikidata.org/entity/Q58486771
Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisStereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with ChloralFunctionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic applicationRate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.Diaminocyclopropenylidene organocatalysts: beyond N-heterocyclic carbenes.Characterization of the key intermediates of carbene-catalyzed umpolung by NMR spectroscopy and X-ray diffraction: breslow intermediates, homoenolates, and azolium enolates.N-tert-butyl triazolylidenes: catalysts for the enantioselective (3+2) annulation of α,β-unsaturated acyl azoliums.Carboranes as Aryl Mimetics in Catalysis: A Highly Active Zwitterionic NHC-Precatalyst.NHC-Organocatalyzed CAr -O Bond Cleavage: Mild Access to 2-Hydroxybenzophenones.Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst.Benzene construction via organocatalytic formal [3+3] cycloaddition reaction.Mechanistic insight into the Staudinger reaction catalyzed by N-heterocyclic carbenes.Conjugate umpolung of β,β-disubstituted enals by dual catalysis with an N-heterocyclic carbene and a Brønsted acid: facile construction of contiguous quaternary stereocenters.Enantioselective synthesis of cyclopenta[b]benzofurans via an organocatalytic intramolecular double cyclization.NHC-organokatalysierte CAr -O-Bindungsspaltung: milder Zugang zu 2-HydroxybenzophenonenProton transfer reactions ofN-aryl triazolium salts: unusualortho-substituent effects
P2860

Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent

Item
http://www.wikidata.org/entity/Q58486771
description
im Januar 2013 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована у 2013
@uk
name
Mechanistic insights into the ...... role of the N-aryl substituent
@en
Mechanistic insights into the ...... role of the N-aryl substituent
@nl
type
label
Mechanistic insights into the ...... role of the N-aryl substituent
@en
Mechanistic insights into the ...... role of the N-aryl substituent
@nl
prefLabel
Mechanistic insights into the ...... role of the N-aryl substituent
@en
Mechanistic insights into the ...... role of the N-aryl substituent
@nl
P1433
P1476
P2093
P2860
P304
P31
P356
P433
P478
P577
P356
P1433
P1476
Mechanistic insights into the ...... role of the N-aryl substituent
@en
P2093
P2860
P304
P31
P356
P433
P478
P577