Copper(I)-Catalyzed Substitution Reactions of Propargylic Amines: Importance of C(sp)−C(sp3) Bond Cleavage in Generation of Iminium Intermediates
about
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.The Redox-A(3) Reaction.Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process.Rh-catalyzed C-C cleavage of benzyl/allylic alcohols to produce benzyl/allylic amines or other alcohols by nucleophilic addition of intermediate rhodacycles to aldehydes and imines.Lanthanide-Catalyzed Reversible Alkynyl Exchange by Carbon-Carbon Single-Bond Cleavage Assisted by a Secondary Amino Group.Allyl-, allenyl-, and propargyl-transfer reactions through cleavage of C-C bonds catalyzed by an N-heterocyclic carbene/copper complex: synthesis of multisubstituted pyrroles.Copper(I)-Catalyzed Deacetylenative Coupling of Propargylic Amines: An Efficient Synthesis of Symmetric 1,4-Diamino-2-butynesCopper-catalyzed C–C bond cleavage and intramolecular cyclization: an approach toward acridones
P2860
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P2860
Copper(I)-Catalyzed Substitution Reactions of Propargylic Amines: Importance of C(sp)−C(sp3) Bond Cleavage in Generation of Iminium Intermediates
description
im April 2010 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 01 April 2010
@en
наукова стаття, опублікована у квітні 2010
@uk
name
Copper(I)-Catalyzed Substituti ...... ation of Iminium Intermediates
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type
label
Copper(I)-Catalyzed Substituti ...... ation of Iminium Intermediates
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prefLabel
Copper(I)-Catalyzed Substituti ...... ation of Iminium Intermediates
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P356
P1476
Copper(I)-catalyzed substituti ...... ation of iminium intermediates
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P2093
Akifumi Kimura
Tsuyuka Sugiishi
P304
P356
10.1021/JA9109055
P407
P577
2010-04-01T00:00:00Z