Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
about
Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.Applications of density functional theory to iron-containing molecules of bioinorganic interest.Accessing Drug Metabolites via Transition-Metal Catalyzed C-H Oxidation: The Liver as Synthetic Inspiration.Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.Mechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases.Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation.Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide.Nonheme iron mediated oxidation of light alkanes with oxone: characterization of reactive oxoiron(IV) ligand cation radical intermediates by spectroscopic studies and DFT calculations.New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation.H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2.Mechanistic elucidation of C-H oxidation by electron rich non-heme iron(IV)-oxo at room temperature.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.Properties and reactivities of nonheme iron(IV)-oxo versus iron(V)-oxo: long-range electron transfer versus hydrogen atom abstraction.Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.A Systematic Account on Aromatic Hydroxylation by a Cytochrome P450 Model Compound I: A Low-Pressure Mass Spectrometry and Computational Study.Correlating DFT-calculated energy barriers to experiments in nonheme octahedral Fe(IV)O species.Comparison of the reactivity of nonheme iron(IV)-oxo versus iron(IV)-imido complexes: which is the better oxidant?Water oxidation catalysed by iron complex of N,N'-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron-oxo intermediates and density functional theory calculations.Diferric oxo-bridged complexes of a polydentate aminopyridyl ligand: synthesis, structure and catalytic reactivityIron-Catalyzed CH Hydroxylation and Olefincis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
P2860
Q34990257-0EE65A58-3D22-4BF6-A444-B573C691615AQ35332343-277F6C23-D9AD-49E4-8313-5CBC4F7FDCF9Q36143079-C06184C8-CBC5-468C-BF9C-6C78C62CCE8DQ38210222-85E30813-2C72-4B80-A0EB-A8D748A23F17Q38977018-B3837DE6-5185-49B9-BF97-2A8F53BF7656Q41973020-E083CA27-64C5-41D3-9696-3672D7D8FCCAQ42068511-24532245-3FBB-4553-B15D-98D37DB931B6Q42952260-1040F940-BC06-4C0A-A21B-18701752B383Q45420797-B9628C33-7DE8-4BA3-B9AB-46006E1B9BE6Q45925751-C78FCFC5-9460-413D-ACFF-3A771C8E4033Q46333359-A4C57908-EC7D-4513-B8A6-B032FFA63CCBQ46367055-D8B180F6-C4FB-4DC7-B9EE-48DEEEA7CCCBQ46678837-11079BBA-B70A-4AAC-AD39-8D9A6F91B194Q46683818-1E30A5AF-DAD0-4D30-983F-A21424157D81Q46685097-E7CB6E6D-83C2-441B-921A-EBA7F5D3EFFAQ46837315-761A623F-53BC-43A0-BA93-892D09F21AC0Q46967923-D9E16E1A-9BDA-4328-956A-8209466ED432Q48054054-850E0DCD-0145-49C6-AE8F-7E5DB87A1CC6Q51352863-A337EEDA-B35B-4D9D-AA06-4001D02538C2Q54614687-A1AD7A97-286E-4EB3-B56F-2B7670DA8D09Q55385657-06EC443E-56C7-423C-A4C1-65971CC9AC53Q58223664-95282005-1E3B-49C2-89A3-A8129373FF16Q59287898-558D4C6F-72F6-436F-8330-9AC795D146F1
P2860
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
description
2009 nî lūn-bûn
@nan
2009 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2009 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
name
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@ast
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@en
type
label
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@ast
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@en
prefLabel
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@ast
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@en
P2093
P2860
P356
P1476
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
@en
P2093
Britt Hedman
Jihae Yoon
Kasi Nehru
Keith O Hodgson
Mi Sook Seo
Samuel A Wilson
Wonwoo Nam
Yu Kyeong Jang
P2860
P304
P356
10.1002/ANIE.200802672
P407
P577
2009-01-01T00:00:00Z