High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
about
Proton-coupled electron transferRecent Advances in Solid Catalysts Obtained by Metalloporphyrins Immobilization on Layered Anionic Exchangers: A Short Review and Some New Catalytic ResultsMoving protons and electrons in biomimetic systemsBiochemistry and theory of proton-coupled electron transferMononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligandsDioxygen Activation at Non-Heme Diiron Centers: Oxidation of a Proximal Residue in the I100W Variant of Toluene/ o -Xylene Monooxygenase Hydroxylase †Sulfide Oxidation by O2: Synthesis, Structure and Reactivity of Novel Sulfide-Incorporated Fe(II) Bis(imino)pyridine ComplexesMechanistic aspects of CYP74 allene oxide synthases and related cytochrome P450 enzymesHeme biomolecule as redox mediator and oxygen shuttle for efficient charging of lithium-oxygen batteriesIntramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesInfrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands.Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.Abiotic methanogenesis from organosulphur compounds under ambient conditions.Revisiting the mechanism of dioxygen activation in soluble methane monooxygenase from M. capsulatus (Bath): evidence for a multi-step, proton-dependent reaction pathway.Sensitivity of X-ray core spectroscopy to changes in metal ligation: a systematic study of low-coordinate, high-spin ferrous complexes.Sulfur versus iron oxidation in an iron-thiolate model complexReactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces.Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexesManganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexesReaction of an iron(IV) nitrido complex with cyclohexadienes: cycloaddition and hydrogen-atom abstractionMechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups.Copper chelation selectively kills colon cancer cells through redox cycling and generation of reactive oxygen speciesExperimentally quantifying small-molecule bond activation using valence-to-core X-ray emission spectroscopyModeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.XAS and DFT investigation of mononuclear cobalt(III) peroxo complexes: electronic control of the geometric structure in CoO2 versus NiO2 systemsTriggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.Theoretical study of the mechanism of oxoiron(IV) formation from H2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transferCharacterization and reactivity of a terminal nickel(III)-oxygen adductMechanism of S-oxygenation by a cysteine dioxygenase model complexTransient Ru-methyl formate intermediates generated with bifunctional transfer hydrogenation catalysts.Tuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Synthesis and characterisation of a mesocyclic tripodal triamine ligand.Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.Axial and equatorial ligand effects on biomimetic cysteine dioxygenase model complexesAxial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstractionPhotolysis of a High-Spin Azidoiron(III) Complex Studied by Time-Resolved Fourier-Transform Infrared Spectroscopy.
P2860
Q24597113-D546FB0B-8325-404A-B001-97158A7726FCQ26764779-73DDF814-F63D-4517-AE0B-01469647A4B3Q26829547-DC30BAB9-157E-453C-82F0-2BF168842B78Q26863530-BFE2AB3B-3C1F-4A4E-8485-1F017D97B8EAQ26865354-A018A7FB-FCAE-4391-9D81-E816332C4C95Q27649158-78E80B00-F32E-4AE4-904D-72DFEB2B242CQ28677812-AF46B14A-768B-4655-BF80-BCA3E8EBFE1BQ28749793-1C5C6B0F-68CC-48C1-B3E3-0C9B1C46CFE4Q28821279-5E4A07EF-F150-4386-A720-C48066843C65Q28834032-6C859624-21EB-441E-9714-421892376819Q30455972-42B3D29F-9331-4A28-A53B-8C9EB0ECEF4DQ30956831-EB9A0B76-B92B-4CC5-9BD5-E5ECF4ADF010Q33462001-DF43E1E6-E842-4B13-A92A-1B65EEE82207Q33554957-0072E299-034B-4113-9779-17D6B14D317BQ33646054-29C7D810-2BC1-4D31-B477-8A5AE97A0169Q33744230-72E7D010-1F16-4D48-AF2B-15A1D67B6143Q33824275-4A43E638-AE20-4F19-83B3-438524B9F2B2Q33853882-C19019D7-2D41-4632-94D5-A6D295CDF286Q33883930-01A2258F-1551-473D-B0BF-1306C8BB956FQ33899773-12E42E99-3486-44B2-B7A5-23A9450718E2Q33992789-0E5D37DB-BB29-4327-B718-8BA2CFA8ED0BQ34017510-EBC2BE54-7837-4C28-BF44-297702E5A3CCQ34070236-511C26DC-BC33-46E6-BEC8-256C0FA2B2BBQ34361066-41448AD8-F198-4A7F-A693-641F0043A091Q34469073-586D5D32-7E04-4A9F-A0EA-8A20F100900EQ34829461-90E11F7F-332F-4E1E-9C0B-DAA32B054A80Q34990257-0A3BEBE1-8A24-4E46-B7B4-EDF313AB1690Q35087473-B1D2E743-8B6F-4FE9-A04A-D478ABF57964Q35102626-C2B56C92-6639-410D-9C73-2FE0C2A81C54Q35104404-63CCEA4E-D672-4325-927C-62FDF638680CQ35462178-CAD1C601-9690-43BB-8CC0-C24FD16D500CQ35701702-56C0272E-3F1D-4989-8A8C-2DFD7601AAF6Q35787115-A7C8C821-8919-4E70-8147-87DD3A2A2A90Q35801360-C0469624-7769-4BA0-BF64-67562911642BQ35815761-D7C625C5-6CE6-4B96-ACCA-7066D94EA50EQ35955713-366FDC9D-29EA-4269-AABB-78D72A8D406FQ36093562-4D8F3645-4016-40A1-95BF-8A1EEEC27011Q36266480-A4194111-4B90-4130-ACC6-DEE9850E1BEAQ36288485-A5F5F9A6-8581-41FB-B5A4-7AC8E63B8C5DQ36332557-17E8433B-05BB-4F5A-9A3E-EEED6B142854
P2860
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
description
2007 nî lūn-bûn
@nan
2007 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի մայիսին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
High-valent iron
@nl
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@ast
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@en
type
label
High-valent iron
@nl
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@ast
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@en
prefLabel
High-valent iron
@nl
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@ast
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@en
P356
P1476
High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.
@en
P304
P356
10.1021/AR700027F
P407
P50
P577
2007-05-01T00:00:00Z