Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
about
[{Au(IPr)}2(μ-OH)]X complexes: synthetic, structural and catalytic studies.Dinuclear gold-silver resting states may explain silver effects in gold(I)-catalysis1,3-Dipolar cycloaddition between a metal-azide (Ph3PAuN3) and a metal-acetylide (Ph3PAuC≡CPh): an inorganic version of a click reaction.Anatomy of gold catalysts: facts and mythsMechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes.Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes.σ-π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis.Stable cyclic carbenes and related species beyond diaminocarbenes.Gold-catalyzed decorations of arenes and heteroarenes with C-C multiple bonds.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.Recent advances in the isolation and reactivity of organogold complexes.Intriguing mechanistic labyrinths in gold(I) catalysis.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with α-ketones.Characterization of vinylgold intermediates: gold-mediated cyclization of acetylenic amides.Synthesis of gem-diaurated species from alkynols.Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynesGold-catalyzed synthesis of tetrazoles from alkynes by C-C bond cleavageA Brief Survey of our Contribution to Stable Carbene Chemistry.Mechanistic study of gold(I)-catalyzed intermolecular hydroamination of allenes.A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene.Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.Catalytic asymmetric synthesis of cyclic ethers containing an α-tetrasubstituted stereocenter.Synthesis and study of cationic, two-coordinate triphenylphosphine-gold-π complexes.Competitive gold-activation modes in terminal alkynes: an experimental and mechanistic study.Straightforward synthetic access to gem-diaurated and digold σ,π-acetylide species.On the Accessible Reaction Channels of Vinyl Gold(I) Species: π- and σ-Pathways.Isolation and characterization of gem-diaurated species having two C-Au σ bonds in gold(i)-activated amidiniumation of alkynes.Synthesis and catalytic applications of 1,2,3-triazolylidene gold(i) complexes in silver-free oxazoline syntheses and C-H bond activation.On the Mechanism of the Digold(I)-Hydroxide-Catalysed Hydrophenoxylation of Alkynes.Dispersion, solvent and metal effects in the binding of gold cations to alkynyl ligands: implications for Au(I) catalysis.Silver-free activation of ligated gold(I) chlorides: the use of [Me3NB12Cl11]- as a weakly coordinating anion in homogeneous gold catalysis.Mechanistic study of gold(I)-catalyzed hydroamination of alkynes: outer or inner sphere mechanism?The mechanism of gold(I)-catalyzed hydroalkoxylation of alkynes: an extensive experimental study.Cationic, two-coordinate gold π complexes.Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective Hydrocarboxylation of Internal Alkynes.Merging gold catalysis, organocatalytic oxidation, and Lewis acid catalysis for chemodivergent synthesis of functionalized oxazoles from N-propargylamides.Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.
P2860
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P2860
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
description
2009 nî lūn-bûn
@nan
2009 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2009 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
name
Mechanistic surprises in the gold
@nl
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@ast
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@en
type
label
Mechanistic surprises in the gold
@nl
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@ast
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@en
prefLabel
Mechanistic surprises in the gold
@nl
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@ast
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.
@en
P2860
P356
P1476
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes
@en
P2093
Dieter Weber
P2860
P304
P356
10.1002/ANIE.200902049
P407
P577
2009-01-01T00:00:00Z